Kinetic features of ammonium persulfate decomposition in aqueous medium

被引：16

作者：

Borisov, I. M. ^{[1
]}

Luksha, R. S. ^{[1
]}

Rashidova, S. T. ^{[1
]}

机构：

[1] M Akmullah Bashkir State Pedag Univ, 3a Ul Oktyabrskoi Revolutsii, Ufa 450000, Bashkortostan, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2015年 / 64卷 / 10期

关键词：

ammonium persulfate; water; decomposition kinetics; rate constant;

D O I：

10.1007/s11172-015-1185-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Decomposition of ammonium persulfate in an aqueous medium (353-368 K) is limited by decomposition of persulfate ions with a rate constant logk(2) = (15 +/- 3) -(52 +/- 8).10(3) J mol(-1)/(2.3RT). The apparent rate constant for decomposition of persulfate ammonium k(app) = = k(2)gamma depends on the decomposition rate constant and the activity coefficient of persulfate ions, the temperature, and the ionic strength of solution.

引用

页码：2512 / 2513

页数：2