Syntheses and properties of waterborne polyurethane-epoxy adhesives

被引：15
作者：
Jeong, Boo Young [1 ]
Cheon, Jung Mi [1 ]
Chun, Jae Hwan [1 ]
机构：
[1] KIFLT, Polymer Surface Res Div, Busan, South Korea
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2016年 / 636卷 / 01期
关键词：
waterborne polyurethane; epoxy; polyester polyol; adhesive; DISPERSIONS;
D O I：
10.1080/15421406.2016.1201397
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this study, waterborne polyurethanes (WPUs) with an epoxy group and improved hydrolysis resistance and adhesion were synthesized using a polyester polyol, epoxy resin, 4,4-dicyclohexylmethane diisocyanate, and dimethylol propionic acid (DMPA). The properties of the WPU were evaluated by differential scanning calorimetry, tensile strength, elongation, hardness and adhesion strength. The glass transition temperature (Tg) of the synthesized WPU was approximately -50 degrees C. The Tg and tensile strength increased with increasing epoxy resin content while the elongation decreased. The optimum adhesion was achieved with a polyol:epoxy ratio of 99:1.
引用
收藏
页码：134 / 141
页数：8
相关论文
共 25 条
  • [1] Ahn J. B., 1989, J KOREAN IND ENG CHE, V8, P230
  • [2] Askari F, 2013, J APPL POLYM SCI, V130, P1743, DOI [10.1002/APP.39299, 10.1002/app.39299]
  • [3] Coutinho FMB, 2001, J APPL POLYM SCI, V80, P566, DOI 10.1002/1097-4628(20010425)80:4<566::AID-APP1131>3.0.CO
  • [4] 2-H
  • [5] Kim K. H., 1998, KOREA J OIL FAT CHEM, V1, P29
  • [6] Kim S. K., 2000, ELASTOMER, V35, P281
  • [7] Kim S. M., 2004, J KOREAN IND ENG CHE, V15, P537
  • [8] PHASE-SEPARATION IN SEGMENTED POLYURETHANES
    KWEI, TK
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1982, 27 (08) : 2891 - 2899
  • [9] Lee D. J., 1999, J KOREAN FIBER SOC, V36, P873
  • [10] Lee J.C., 1995, POLYM-KOREA, V19, P223
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