(4,4)- and (6,3)-2-D luminescent lanthanide(III) metal-organic frameworks constructed from tetrafluorosuccinate and 1,10-phenanthroline

被引：16

作者：

Li, Xia ^{[1
]}

Zhang, Yan-Bin ^{[1
]}

Shi, Mei ^{[2
]}

Li, Pei-Zhou ^{[1
]}

机构：

[1] Capital Normal Univ, Dept Chem, Beijing 100037, Peoples R China

[2] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 08期

关键词：

lanthanide coordination polymer; tetrafluorosuccinate; hydrothermal synthesis; crystal structure; luminescence;

D O I：

10.1016/j.inoche.2008.04.016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new coordination polymers [Eu(2)(TFSA)(3)(phen)(2)](n) (1) and [Tb(2)(TFSA)(3)(phen)(4)(H(2)O)(2)](n) (2) (TFSA = tetrafluorosuccinate, phen = 1,10-phenanthroline) have been synthesized and structurally characterized. The 1 has a 2-D grid-like network structure with (4,4) topology and the 2 has a 2-D honeycomb-like network structure with (6,3) topology. The two complexes exhibit strong photoluminescence of the Eu(III) for 1 and Tb(III) for 2, respectively. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：869 / 872

页数：4

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