(4,4)- and (6,3)-2-D luminescent lanthanide(III) metal-organic frameworks constructed from tetrafluorosuccinate and 1,10-phenanthroline

被引：16

作者：

Li, Xia ^{[1
]}

Zhang, Yan-Bin ^{[1
]}

Shi, Mei ^{[2
]}

Li, Pei-Zhou ^{[1
]}

机构：

[1] Capital Normal Univ, Dept Chem, Beijing 100037, Peoples R China

[2] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 08期

关键词：

lanthanide coordination polymer; tetrafluorosuccinate; hydrothermal synthesis; crystal structure; luminescence;

D O I：

10.1016/j.inoche.2008.04.016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new coordination polymers [Eu(2)(TFSA)(3)(phen)(2)](n) (1) and [Tb(2)(TFSA)(3)(phen)(4)(H(2)O)(2)](n) (2) (TFSA = tetrafluorosuccinate, phen = 1,10-phenanthroline) have been synthesized and structurally characterized. The 1 has a 2-D grid-like network structure with (4,4) topology and the 2 has a 2-D honeycomb-like network structure with (6,3) topology. The two complexes exhibit strong photoluminescence of the Eu(III) for 1 and Tb(III) for 2, respectively. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：869 / 872

页数：4

共 25 条

[1] Silver coodination polymers with flexible ligands.: Syntheses, crystal structures, and effect of the counteranion and the solvent on the structure of complexes [AgL1X]∞ of the bis(phenylthio)methane ligand L1 with silver(I) salts, X = ClO4-, BF4-, CF3COO-, CF3SO3-, CF3CF2CF2COO-, and -OOCCF2CF2COO-
Awaleh, MO
Badia, A
Brisse, F
[J]. CRYSTAL GROWTH & DESIGN, 2005, 5 (05) : 1897 - 1906
[2] Bunzil J.-C. G., 1989, LANTHANIDE PROBES LI
[3] Enhanced near-infrared-luminescence in an erbium tetrafluoroterephthalate framework
Chen, Banglin
Yang, Yu
Zapata, Fatima
Qian, Guodong
Luo, Yongshi
Zhang, Jiahua
Lobkovsky, Emil B.
[J]. INORGANIC CHEMISTRY, 2006, 45 (22) : 8882 - 8886
[4] An equilibrium between a loop and a triangle containing Mo24+ species and perfluorodicarboxylate linkers
Cotton, F. Albert
Murillo, Carlos A.
Yu, Rongmin
[J]. INORGANICA CHIMICA ACTA, 2006, 359 (15) : 4811 - 4820
[5] Toward templated metal-organic frameworks: Synthesis, structures, thermal properties, and luminescence of three novel lanthanide-adipate frameworks
de Lill, DT
Gunning, NS
Cahill, CL
[J]. INORGANIC CHEMISTRY, 2005, 44 (02) : 258 - 266
[6] Ghosh S. K., 2007, ANGEW CHEM, V119, P8111
[7] Girginova PI, 2007, EUR J INORG CHEM, P4238
[8] A coordination network that catalyzes O2-based oxidations
Han, Jong Woo
Hill, Craig L.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (49) : 15094 - +
[9] Lithium-doped metal-organic frameworks for reversible H2 storage at ambient temperature
Han, Sang Soo
Goddard, William A., III
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (27) : 8422 - +
[10] Unusual magnetic behavior of a 2D citrate-bridged dysprosium(III) coordination polymer
Li, Feng-Yan
Xu, Lin
Gao, Guang-Gang
Fan, Li-Hua
Bi, Bo
[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, (21) : 3405 - 3409

← 1 2 3 →