Coordinatively unsaturated metal sites (open metal sites) in metal-organic frameworks: design and applications

被引：636

作者：

Kokcam-Demir, Ulku ^{[1
]}

Goldman, Anna ^{[1
]}

Esrafili, Leili ^{[2
]}

Gharib, Maniya ^{[2
]}

Morsali, Ali ^{[2
]}

Weingart, Oliver ^{[3
]}

Janiak, Christoph ^{[1
]}

机构：

[1] Heinrich Heine Univ Dusseldorf, Inst Anorgan Chem & Strukt Chem, D-40204 Dusseldorf, Germany

[2] Tarbiat Modares Univ, Fac Sci, Dept Chem, POB 14115-175, Tehran, Iran

[3] Heinrich Heine Univ Dusseldorf, Inst Theoret Chem & Camp Chem, D-40204 Dusseldorf, Germany

来源：

CHEMICAL SOCIETY REVIEWS | 2020年 / 49卷 / 09期

关键词：

CARBON-DIOXIDE ADSORPTION; DENSITY-FUNCTIONAL THEORY; HYDROGEN STORAGE PROPERTIES; SELECTIVE GAS-ADSORPTION; NITRIC-OXIDE ADSORPTION; MONTE-CARLO SIMULATIONS; HIGH-CAPACITY HYDROGEN; HIGH ACETYLENE STORAGE; HIGH METHANE STORAGE; HIGH H-2 ADSORPTION;

D O I：

10.1039/c9cs00609e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-organic frameworks (MOFs) can contain open metal sites (OMS) or coordinatively unsaturated sites (CUS) or open coordination sites (OCS) when vacant Lewis acid sites on the metal ions or cluster nodes have been generated. This review combines for the first time all aspects of OMS in MOFs, starting from different preparation strategies over theoretical studies on the effects of OMS with host-guest interactions up to distinct OMS-MOF applications. In the experimental part the focus of this review is on MOFs with proven OMS formation which are not only invoked but are clearly verified by analytical methods.

引用

页码：2751 / 2798

页数：48

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