Epoxidation of chiral camphor N-enoylpyrazolidinones with methyl(trifluoromethyl)dioxirane and urea hydrogen peroxide/acid anhydride:: Reversal of stereoselectivity

被引：26
作者：
Fan, CL [1 ]
Lee, WD [1 ]
Teng, NW [1 ]
Sun, YC [1 ]
Chen, KM [1 ]
机构：
[1] Natl Taiwan Normal Univ, Dept Chem, Taipei 116, Taiwan
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 68卷 / 25期
关键词：
D O I：
10.1021/jo034807w
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Both diastereomeric isomers of epoxides with high optical purity are obtained when camphor N-methacryl-oylpyrazolidinone (1a) and N-tigloylpyrazolidinone (1b) are treated with a urea hydrogen peroxide/TFAA and methyl(trifluoromethyl)dioxirane, respectively.
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收藏
页码：9816 / 9818
页数：3
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