Synthesis, Crystal Structure and Properties of a New Manganese(II) Complex with Mucic Acid

被引：0
|
作者：
Lue Yao-Kang [1 ]
Feng Yun-Long [1 ]
Zhan Cai-Hong [1 ]
Chen Jing [1 ]
Wang Xiao-Juan [1 ]
Jiang Zhan-Guo [1 ]
机构：
[1] Zhejiang Normal Univ, Inst Phys Chem, Zhejiang Key Lab React Chem Solid Surfaces, Jinhua 321004, Zhejiang, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2011年 / 27卷 / 04期
关键词：
manganese(II) complex; mucic acid; crystal structure; nickel hydroxide electrode; additive; ORGANIC FRAMEWORK; NICKEL-HYDROXIDE; METAL-IONS; GALACTARATE; ELECTRODES; NI(OH)(2); DISCHARGE; LIGAND;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new manganese complex [Mn(muc)(H2O)(3)] center dot H2O (1) (H(2)muc=mucic acid) has been synthesized and characterized by X-ray single-crystal diffraction, elemental analysis, IR spectrum, and thermogravimetry analysis. The structure of 1 is composed of 1D chains and further joined by hydrogen bonds to construct a 3D supramolecule structure. Preliminary electrochemical experiments indicated that as an additive on nickel hydroxide electrodes 1 could improve the electrochemical performance and has potential applications in electrochemical storage. CCDC: 720478.
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页码：791 / 796
页数：6
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