Synthesis, characterisation and crystal structure of a novel nickel(II) phosphine complex, trans-[Ni2Cl4{cis-(Cy2PCH2)2C6H4}2]

被引：10

作者：

Johnson, Magnus T. ^{[1
]}

Wendt, Ola F. ^{[1
]}

机构：

[1] Lund Univ, Dept Chem, S-22100 Lund, Sweden

来源：

INORGANICA CHIMICA ACTA | 2011年 / 367卷 / 01期

基金：

瑞典研究理事会;

关键词：

Nickel; Phosphine; Cyclometallation; Pincer ligands; DIPHOSPHINITO POCOP COMPLEXES; PINCER COMPLEXES; HYDRIDE COMPLEXES; BOND ACTIVATION; CYCLOMETALATION; COORDINATION; REACTIVITY; CATALYSTS; LIGANDS;

D O I：

10.1016/j.ica.2010.12.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 1,3-C6H4(CH2PCy2)(2) with anhydrous nickel(II) chloride in dry THF produces the non-cyclometallated dinuclear complex trans-[Ni2Cl4{cis-(Cy2PCH2)(2)C6H4}(2)]. The compound was characterised by H-1, P-31 and C-13 NMR spectroscopy and its solid state structure was determined by X-ray diffraction. An improved synthetic procedure of the aromatic pincer ligand 1,3-C6H4(CH2PCy2)(2) is reported. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：222 / 224

页数：3

共 24 条

[1]

Albrecht M, 2001, ANGEW CHEM INT EDIT, V40, P3750, DOI 10.1002/1521-3773(20011015)40:20<3750::AID-ANIE3750>3.0.CO

[2]

2-6

[3] Transcyclometalation processes with late transition metals:: Caryl-H bond activation via noncovalent C-H•••interactions [J].