Terminal Iron Dinitrogen and Iron Imide Complexes Supported by a Tris(phosphino)borane Ligand

被引：213

作者：

Moret, Marc-Etienne ^{[1
]}

Peters, Jonas C. ^{[1
]}

机构：

[1] CALTECH, Div Chem & Chem Engn, Pasadena, CA 91125 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 09期

基金：

瑞士国家科学基金会;

关键词：

iron; metallaboratranes; multiple bonds; nitrogen fixation; phosphinoborane ligands; DATIVE SIGMA-BOND; STRUCTURAL-CHARACTERIZATION; CATALYTIC-REDUCTION; NITROGEN-FIXATION; NITRIDO COMPLEX; FE-IVN; BORANE; METALLABORATRANES; REACTIVITY; AMMONIA;

D O I：

10.1002/anie.201006918

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Adaptable metallaboratranes: A tris- (phosphino)borane ligand stabilizes both low-valent Fei-N2 complexes and a mid-valent imido species with a Feï£NAr bond, thanks to its ability to shuttle between trigonal-bipyramidal and pseudotetrahedral geometries by elongation of the apical iron-boron bond (see picture). © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2063 / 2067

页数：5

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