Metal-Organic Framework Thin Film-Based Dye Sensitized Solar Cells with Enhanced Photocurrent

被引：21

作者：

Ahmad, Shargeel ^{[1
]}

Liu, Jinxuan ^{[1
]}

Ji, Wei ^{[1
]}

Sun, Licheng ^{[1
,2
]}

机构：

[1] Dalian Univ Technol, Inst Artificial Photosynthesis, State Key Lab Fine Chem, Dalian 116024, Peoples R China

[2] KTH Royal Inst Technol, Sch Chem Sci & Engn, Dept Chem, S-10044 Stockholm, Sweden

来源：

MATERIALS | 2018年 / 11卷 / 10期

关键词：

surface supported metal organic framework; triplet-triplet annihilation upconversion; triplet-triplet energy transfer; dye sensitized solar cell; TRIPLET-TRIPLET ANNIHILATION; PHOTON-UP-CONVERSION; SELF-ASSEMBLED BILAYERS; VISIBLE-LIGHT; EFFICIENCY; BODIPY; ENERGY; GENERATION; REDUCTION; STATE;

D O I：

10.3390/ma11101868

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Metal-organic framework thin film-based dye sensitized solar cell is fabricated with highly oriented, crystalline, and porous Zn-perylene metal-organic framework (MOF) thin film (SURMOF) which is integrated with Bodipy embedded in poly(methyl methacrylate). It has been demonstrated that the photocurrent can be enhanced by a factor of 5 relative to Zn-perylene MOF thin film due to triplet-triplet annihilation up-conversion between the Bodipy/PMMA sensitizer and the Zn-perylene MOF thin film acceptor using Co(bpy)(3)(2+/3+) as redox mediator.

引用

页数：8

共 34 条

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