A One-Pot Synthesis of Hydrogen and Carbon Fuels from Water and Carbon Dioxide

被引：40

作者：

Li, Fang-Fang ^{[1
]}

Liu, Shuzhi ^{[1
]}

Cui, Baochen ^{[1
]}

Lau, Jason ^{[1
]}

Stuart, Jessica ^{[1
]}

Wang, Baohui ^{[1
]}

Licht, Stuart ^{[1
]}

机构：

[1] George Washington Univ, Dept Chem, Washington, DC 20052 USA

来源：

ADVANCED ENERGY MATERIALS | 2015年 / 5卷 / 07期

关键词：

THERMAL ELECTROCHEMICAL PRODUCTION; MOLTEN AIR; IRON; CO2; ELECTROLYSIS; CAPTURE;

D O I：

10.1002/aenm.201401791

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A single-pot electrolytic synthesis of hydrogen and carbon fuels is achieved through the use of a mixed, hydroxide/carbonate electrolyte, nickel anode (generating O2), and nickel or steel cathode (generating graphite and hydrogen). Low hydroxide fractions in the electrolyte ensure efficient carbon formation, while high fractions form only H2 at the cathode; added barium and lithium salts ensure effective nickel anode stability. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页数：7

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