Synthesis, structural characterization and reactivity towards phenol of a bis(silyl) platinum(II) complex

被引：2

作者：

Sun, Shuang-Shuang

Guo, Jin-Fei

Wang, Shi ^{[1
]}

Huang, Chao

Zhu, Jia-Yi

Li, Yong-Hua ^{[1
]}

Huang, Wei

机构：

[1] Nanjing Univ Posts & Telecommun, Natl Synerget Innovat Ctr Adv Mat SICAM, Key Lab Organ Elect & Informat Displays, Nanjing 210023, Jiangsu, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2016年 / 451卷

基金：

中国国家自然科学基金;

关键词：

Chelating; Silyl; Platinum; Phenol; Multinuclear NMR; H BOND ACTIVATION; TRANSITION-METAL-COMPLEXES; SI-H; PALLADIUM COMPLEXES; SILYLENE COMPLEXES; SILICON; LIGANDS; DINUCLEAR; RHODIUM; STATE;

D O I：

10.1016/j.ica.2016.07.024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 1,2-C6H4(SiMe2H)(SiH3) (1) with Pt(dmpe)(PEt3)(2) (dmpe = Me2PCH2CH2PMe2) in the ratio of 1:1 yields the complex {1,2-C6H4(SiMe2)(SiH2)} Pt-II(dmpe) (2), which has unique reactivity towards sterically unhindered phenol to form an unusual diphenoxy substituted (bis) silyl platinum(II) compound (3). Only 6 examples of bis(silyl) platinum(II) complexes prepared from this chelating hydrosilane ligand have been registered in the Cambridge Structural Database. The structure of complex (3) was unambiguously determined by single crystal X-ray analysis and multinuclear NMR spectroscopic studies. (C) 2016 Elsevier B. V. All rights reserved.

引用

页码：157 / 161

页数：5

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