Oxidative dehydrogenation of 5-(pyridine-2-yl-methyl)-2-thioxo-4-imidazolidinones in complexation reaction with copper(II) chloride

被引：9

作者：

Majouga, Alexander G. ^{[1
,2
]}

Beloglazkina, Elena K. ^{[1
,2
]}

Yudina, Anna V. ^{[1
]}

Mironov, Andrei V. ^{[1
]}

Zyk, Nikolay V. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Leninskie Gory, Russia

[2] Natl Univ Sci & Technol MISIS MISiS, Moscow 119049, Russia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2015年 / 51卷

基金：

俄罗斯基础研究基金会;

关键词：

Copper complexes; Ligand oxidation; Dehydration; ALKANE-DEHYDROGENATION; IRIDIUM; LIGAND; IRON; HYDROXYLATION; PROMOTION; DIOXYGEN; ENZYMES;

D O I：

10.1016/j.inoche.2014.11.021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The treatment of 5-(pyridine-2-yl-methyl)-2-thioxo-4-imidazolidinones with copper(II) chloride dihydrate led to the formation of a dinuclear copper complex L2Cu2Cl where L is a dehydrogenated initial organic ligand. X-ray diffraction analysis indicated that the starting 3,5-dihydro-4H-imidazole-4-ones undergo oxidation in the course of the reaction with the formation of an exocyclic double bond at C5 position. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：114 / 117

页数：4

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