Solvent-dependent 44 square grid and 64.82 NbO frameworks formed by Cu(Pyac)2 (bis[3-(4-pyridyl)pentane-2,4-dionato]copper(II))

被引:164
作者
Chen, BL [1 ]
Fronczek, FR [1 ]
Maverick, AW [1 ]
机构
[1] Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USA
关键词
D O I
10.1039/b305457h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound crystallizes from anhydrous solvents in a simple square-grid topology, but when water is present, crystals form with an unusual interpenetrated 3D NbO topology whose pores contain hydrogen-bonded solvent molecules.
引用
收藏
页码:2166 / 2167
页数:2
相关论文
共 29 条
[1]   SYSTEMATIC ANALYSIS OF STRUCTURAL DATA AS A RESEARCH TECHNIQUE IN ORGANIC-CHEMISTRY [J].
ALLEN, FH ;
KENNARD, O ;
TAYLOR, R .
ACCOUNTS OF CHEMICAL RESEARCH, 1983, 16 (05) :146-153
[2]  
[Anonymous], UNPUB
[3]  
Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO
[4]  
2-Z
[5]   Inorganic crystal engineering using self-assembly of tailored building-blocks [J].
Blake, AJ ;
Champness, NR ;
Hubberstey, P ;
Li, WS ;
Withersby, MA ;
Schröder, M .
COORDINATION CHEMISTRY REVIEWS, 1999, 183 :117-138
[6]   An unprecedented triply interpenetrated chiral network of 'square-planar' metal centres from the self-assembly of copper(II) nitrate and 1,2-bis(4-pyridyl)ethyne [J].
Carlucci, L ;
Ciani, G ;
Macchi, P ;
Proserpio, DM .
CHEMICAL COMMUNICATIONS, 1998, (17) :1837-1838
[7]   A three-dimensional nanoporous flexible network of 'square-planar' copper(II) centres with an unusual topology [J].
Carlucci, L ;
Cozzi, N ;
Ciani, G ;
Moret, M ;
Proserpio, DM ;
Rizzato, S .
CHEMICAL COMMUNICATIONS, 2002, (13) :1354-1355
[8]   Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].
Eddaoudi, M ;
Moler, DB ;
Li, HL ;
Chen, BL ;
Reineke, TM ;
O'Keeffe, M ;
Yaghi, OM .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330
[9]   Cu2[o-Br-C6H3(CO2)2]2(H2O)2•(DMF)8(H2O)2:: A framework deliberately designed to have the NbO structure type [J].
Eddaoudi, M ;
Kim, J ;
O'Keeffe, M ;
Yaghi, OM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (03) :376-377
[10]   Crystal engineering of NLO materials based on metal-organic coordination networks [J].
Evans, OR ;
Lin, WB .
ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) :511-522