Multi-color resonance ionization of laser ablated gadolinium at high laser power

被引：11
作者：
Maul, J
Eberhardt, K
Huber, G
Karpuk, S
Passler, G
Roca-Saiz, MC
Strachnov, I
Trautmann, N
Wendt, K
机构：
[1] Johannes Gutenberg Univ Mainz, Inst Phys, D-55099 Mainz, Germany
[2] Johannes Gutenberg Univ Mainz, Inst Kernchem, D-55099 Mainz, Germany
来源：
OPTICS COMMUNICATIONS | 2005年 / 256卷 / 4-6期
关键词：
laser ablation; resonance ionization spectroscopy; MALDI-TOF;
D O I：
10.1016/j.optcom.2005.06.088
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
Spectroscopic and analytical properties of a trace analytical method using multi-step resonance ionization at high laser intensities (>kW/cm(2)) have been investigated with gadolinium as it test element. Strongly saturated transitions are observed, which have been used for a temperature determination of the atoms in the laser ablated plume. Regimes of multi-step resonance ionization and multiphoton ionization Could be distinguished, Analytical performances due to resonance enhancement and resulting discrimination against non-resonant background, precision in isotope ratio determination and overall detection efficiency are discussed. (c) 2005 Published by Elsevier B.V.
引用
收藏
页码：364 / 372
页数：9
相关论文
共 17 条
[1]   Trace determination of gadolinium in biomedical samples by diode laser-based multi-step resonance ionization mass spectrometry [J].
Blaum, K ;
Geppert, C ;
Schreiber, WG ;
Hengstler, JG ;
Müller, P ;
Nörtershäuser, W ;
Wendt, K ;
Bushaw, BA .
ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2002, 372 (7-8) :759-765
[2]  
Blaum K, 2000, EUR PHYS J D, V11, P37, DOI 10.1007/s100530070103
[3]   DETECTION OF LASER-ABLATED CESIUM ATOMS WITH RESONANCE IONIZATION AND TIME-OF-FLIGHT MASS-SPECTROMETRY [J].
DUCKWORTH, A ;
ADRAIN, RS ;
TOZER, BA .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1991, 24 (11) :1925-1932
[4]   Resonance ionization mass spectroscopy for trace determination of plutonium in environmental samples [J].
Erdmann, N ;
Herrmann, G ;
Huber, G ;
Kohler, S ;
Kratz, JV ;
Mansel, A ;
Nunnemann, M ;
Passler, G ;
Trautmann, N ;
Turchin, A ;
Waldek, A .
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1997, 359 (4-5) :378-381
[5]  
HUBER G, 2003, HDB RADIOACTIVITY AN, P801
[6]   Measurement of the populations of metastable levels in gadolinium vapor by diode laser-based UV and near-IR absorption spectroscopy [J].
Jung, EC ;
Ko, KH ;
Rho, SP ;
Lim, C ;
Kim, CJ .
OPTICS COMMUNICATIONS, 2002, 212 (4-6) :293-300
[7]   Efficient three-step, two-color ionization of plutonium using a resonance enhanced 2-photon transition into an autoionizing state [J].
Kunz, P ;
Huber, G ;
Passler, G ;
Trautmann, N .
EUROPEAN PHYSICAL JOURNAL D, 2004, 29 (02) :183-188
[8]  
LETHOKOV VS, 1987, LASER PHOTIONIZATION, P71
[9]   Bimodal velocity distribution of atoms released from nanosecond ultraviolet laser ablation [J].
Maul, J ;
Karpuk, S ;
Huber, G .
PHYSICAL REVIEW B, 2005, 71 (04)
[10]   A laser desorption/resonance enhanced photoionisation TOF-system for the spatially resolved trace analysis of elements [J].
Maul, J ;
Berg, T ;
Eberhardt, K ;
Hoog, I ;
Huber, G ;
Karpuk, S ;
Passler, G ;
Strachnov, I ;
Trautmann, N ;
Wendt, K .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2004, 226 (04) :644-650
12