Rheological properties of poly(ethylene glycol) solutions and gels

被引:2
|
作者
Brikov, A. V. [1 ]
Markin, A. N. [2 ]
Sukhoverkhov, S. V. [2 ]
Avramenko, V. A. [2 ]
机构
[1] Sakhalin Energy Investment Co Ltd, Yuzhno Sakhalinsk Head Off, Ul Dzerzhinskogo 35, Yuzhno Sakhalinsk 693020, Russia
[2] Russian Acad Sci, Inst Chem, Far East Div, Pr Stoletiya Vladivostoka 159, Vladivostok 690022, Russia
关键词
D O I
10.1134/S0012501616080030
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
By the interaction of a water-glycol solution of poly(ethylene glycol) (PEG) with calcium chloride dihydrate, a gel was produced. It was determined that, below a certain shear rate, this gel is a Newtonian fluid; however, above a certain shear rate, which depends on the gel viscosity, the properties of this gel are anomalous: the gel flow instantaneously completely stops. The viscosity of the gels was found to exponentially increase with increasing concentration of the cross-linking metal at constant PEG concentration. The density of the gels linearly increases with increasing concentration of the cross-linking metal at constant PEG concentration.
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页码:121 / 123
页数:3
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