Phosphine-free perfluoro-tagged palladium nanoparticles supported on fluorous silica gel: Application to the Heck reaction

被引：64

作者：

Bernini, Roberta ^{[2
]}

Cacchi, Sandro ^{[1
]}

Fabrizi, Giancarlo ^{[1
]}

Forte, Giovanni ^{[3
]}

Niembro, Sandra ^{[4
]}

Petrucci, Francesco ^{[3
]}

Pleixats, Roser ^{[4
]}

Prastaro, Alessandro ^{[2
]}

Sebastian, Rosa Maria ^{[4
]}

Soler, Roger ^{[4
]}

Tristany, Mar ^{[4
]}

Vallribera, Adelina ^{[4
]}

机构：

[1] Univ Roma La Sapienza, Dipartimento Study Chim & Tecnol Sostanze BA, I-0185 Rome, Italy

[2] Univ Tuscia, Dipartimento ABAC, Consorzio Univ La Chim Ambiente, I-01100 Viterbo, Italy

[3] Ist Super Sanita, I-00161 Rome, Italy

[4] Univ Autonoma Barcelona, Dept Chem, E-08193 Cerdanyola Del Valles, Spain

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 04期

关键词：

D O I：

10.1021/ol7024845

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The immobilization of phosphine-free perfluoro-tagged palladium nanoparticles Pd-1 on fluorous silica gel (FSG) and their utilization in the Heck reaction have been investigated. High yields of vinylic substitution products have been obtained. Recycling studies have shown that the solid-supported palladium catalyst can be readily recovered and reused several times without significant loss of activity. Reactions and recovery of the solid-supported palladium catalyst system can be carried out in the presence of air, without any particular precaution.

引用

页码：561 / 564

页数：4

共 28 条

[21] 15-membered triolefinic macrocycles as stabilizers of palladium(0) nanoparticles [J].