Selection of rigid N-donor ligands influence the dimensions and luminescences of five new Cd(II) coordination polymers, based on a flexible tricarboxylic acid

被引：15
|
作者：
Huang, Wen-Huan [1 ,2 ]
Wang, Yao-Yu [1 ]
Zhang, Ya-Nan [2 ]
Liu, Tong [2 ]
Liu, Shu-Ya [2 ]
Wang, Yan-Xin [2 ]
Pang, Ling-Yan [1 ]
Kang, Yi-Fan [1 ]
Li, Jiang [1 ]
机构：
[1] Northwest Univ, Coll Chem & Mat Sci, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ,Shaanxi Key Lab Physicoinorgan Chem, Xian 710069, Peoples R China
[2] Shaanxi Univ Sci & Technol, Coll Chem & Chem Engn, Xian 710021, Shaanxi, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2015年 / 433卷
基金：
中国国家自然科学基金;
关键词：
Coordination polymer; Molecular configuration; Rigid N-donor ligands; Dimension; Luminescence; METAL-ORGANIC FRAMEWORKS; ADSORPTION PROPERTIES; SOLVENT-SIZE; ISOMERISM; CONSTRUCTION; REACTIVITY; COMPLEXES; CHANNELS; LINKERS; ZN(II);
D O I：
10.1016/j.ica.2015.04.027
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In this article, it has used four rigid bidentate N-donor ligands (phen = phenanthroline, 2,2'-bipy = 2,2'-bipyridine, 4,4'-bipy = 4,4'-bipyridine, bpe = 1,2-bis(4-pyridyl)ethene) reacted with the Cd(II) ions and flexible ligand 4,4'-((5-carboxy-1,3-phenylene)bis(oxy)) dibenzoic acid (H(3)cpbda), and successfully synthesized five complexes with different dimensions and luminescence properties. In addition to the "T" and "Y" shaped molecular configurations of H(3)cpbda, the "M" shaped molecular configuration is found for the first time. Three types of molecular configurations act various roles to assemble different dimensional structures. Furthermore, the influence of two different kinds of rigid bidentate N-donor ligands on dimensions and luminescence properties has been studied. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：52 / 62
页数：11
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