The Structure of the Aluminum Fumarate Metal-Organic Framework A520

被引：240

作者：

Alvarez, Elsa ^{[1
,2
,3
]}

Guillou, Nathalie ^{[1
]}

Martineau, Charlotte ^{[1
]}

Bueken, Bart ^{[5
]}

Van de Voorde, Ben ^{[5
]}

Le Guillouzer, Clement ^{[2
]}

Fabry, Paul ^{[1
]}

Nouar, Farid ^{[1
]}

Taulelle, Francis ^{[1
]}

de Vos, Dirk ^{[5
]}

Chang, Jong-San ^{[6
,7
]}

Cho, Kyoung Ho ^{[6
]}

Ramsahye, Naseem ^{[4
]}

Devic, Thomas ^{[1
]}

Daturi, Marco ^{[2
]}

Maurin, Guillaume ^{[4
]}

Serre, Christian ^{[1
]}

机构：

[1] Univ Versailles, Inst Lavoisier Versailles, UMR CNRS 8180, F-78035 Versailles, France

[2] Univ Caen, Lab Catalyse & Spectrochim, ENSICAEN, CNRS, F-14050 Caen, France

[3] DSTF SEPC STEP, PSA Peugeot Citroen Direct Sci & Technol Futures, F-78943 Velizy Villacoublay, France

[4] Univ Montpellier, Inst Charles Gerhardt Montpellier UMR CNRS UM ENS, F-34095 Montpellier 05, France

[5] Katholieke Univ Leuven, Ctr Surface Chem & Catalysis, B-3001 Leuven, Belgium

[6] KRICT, Catalysis Ctr Mol Engn, Taejon 305600, South Korea

[7] Sungkyunkwan Univ, Dept Chem, Suwon 440476, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2015年 / 54卷 / 12期

关键词：

aluminum fumarate; metal-organic frameworks; modeling; solid state NMR spectroscopy; X-ray diffraction; INDUSTRIAL APPLICATIONS; DECOMPOSITION; ETHANOL; SOLIDS; MIL-53;

D O I：

10.1002/anie.201410459

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of the commercially available aluminum fumarate sample A520 has been optimized and its structure analyzed through a combination of powder diffraction, solid-state NMR spectroscopy, molecular simulation, IR spectroscopy, and thermal analysis. A520 is an analogue of the MIL-53(Al)-BDC solid, but with a more rigid behavior. The differences between the commercial and the optimized samples in terms of defects have been investigated by in situ IR spectroscopy and correlated to their catalytic activity for ethanol dehydration.

引用

页码：3664 / 3668

页数：5

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