Aqua(2,4-dimethylpyridine-N)(N-salicylideneglycinato-O,N,O′)copper(II)

被引:17
作者
Warda, SA [1 ]
机构
[1] Univ Marburg, Dept Chem, D-35032 Marburg, Germany
关键词
D O I
10.1107/S0108270197019367
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Cu-II atom of the title complex, [Cu(C9H7NO3)(C7H9N)(H2O)], has a square-pyramidal coordination sphere with a tridentate N-salicylideneglycinato Schiff base dianion and a 2,4-dimethylpyridine ligand bound in the basal plane. The apex of the pyramid is occupied by an O atom from the coordinated water molecule at an apical distance of 2.416 (2) Angstrom. The monomeric moieties in the crystal are stabilized through hydrogen bonding, building a two-dimensional network. The copper(II) polyhedra are arranged in two magnetically inequivalent orientations, leading to a slightly distorted ferrodistortive coupled g tensor.
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页码:768 / 770
页数:3
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