Intramolecular proton transfer of a 2-(2′,4′-dinitrobenzyl)pyridine studied by femtosecond transient absorption spectroscopy

被引:12
作者
Takeda, J [1 ]
Chung, DD [1 ]
Zhou, JP [1 ]
Nelson, KA [1 ]
机构
[1] Yokohama Natl Univ, Fac Engn, Dept Phys, Yokohama, Kanagawa 2408501, Japan
关键词
D O I
10.1016/S0009-2614(98)00506-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The photochromic intramolecular proton transfer in 2-(2',4'-dinitrobenzyl)pyridine was investigated by femtosecond pump-probe transient absorption spectroscopy. Three different transient absorption spectra were observed depending on the delay time between the pump and probe beams. Based on the analysis of the observed spectra, the reaction time of the intramolecular proton transfer of this material was estimated to be 320 similar to 500 fs. (C) 1998 Published by Elsevier Science B.V. AU rights reserved.
引用
收藏
页码:341 / 348
页数:8
相关论文
共 50 条
[41]   Adiabatic intramolecular hydrogen atom transfer in 2-[2-(2-pyrrolyl)ethenyl]pyridine [J].
Obi, M ;
Sakuragi, H ;
Arai, T .
CHEMISTRY LETTERS, 1998, (02) :169-170
[42]   SYNTHESIS OF PHOTOCHROMIC 2-(2',4'-DINITROBENZYL)-PYRIDINES [J].
KLEMM, D ;
KLEMM, E ;
WINKELMANN, S ;
HORHOLD, HH .
JOURNAL FUR PRAKTISCHE CHEMIE, 1975, 317 (05) :761-770
[43]   Photophysics of 2-(4′-Amino-2′-hydroxyphenyI)-1H-imidazo-[4,5-c]pyridine and Its Analogues: Intramolecular Proton Transfer versus Intramolecular Charge Transfer [J].
Behera, Santosh Kumar ;
Karak, Ananda ;
Krishnamoorthy, G. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2015, 119 (06) :2330-2344
[44]   REACTION-MECHANISM OF PHOTOCHROMIC 2-(2',4'-DINITROBENZYL) PYRIDINE (DNBP) SINGLE-CRYSTALS [J].
SIXL, H ;
WARTA, R .
CHEMICAL PHYSICS, 1985, 94 (1-2) :147-155
[45]   The photoinduced intramolecular proton transfer in 2-(2′-hydroxyphonyl)-4-methyloxazole embedded in β-cyclodextrin [J].
Casadesüs, R ;
Moreno, M ;
Lluch, JM .
CHEMICAL PHYSICS LETTERS, 2002, 356 (3-4) :423-430
[46]   Ultrafast dynamics of dual fluorescence of 2-(2′-hydroxyphenyl) benzothiazole and its derivatives by femtosecond transient absorption spectroscopy [J].
Yang, Yonggang ;
Zhang, Qi ;
Liu, Yang ;
Jiang, Zhinan ;
Qin, Chaochao ;
Jiang, Kai ;
Liu, Yufang .
JOURNAL OF LUMINESCENCE, 2022, 248
[47]   Excited-state intramolecular proton transfer of 2-acetylindan-1,3-dione studied by ultrafast absorption and fluorescence spectroscopy [J].
Verma, Pramod Kumar ;
Steinbacher, Andreas ;
Schmiedel, Alexander ;
Nuernberger, Patrick ;
Brixner, Tobias .
STRUCTURAL DYNAMICS-US, 2016, 3 (02)
[48]   MOLECULAR ORBITAL STUDY OF PHOTOTROPISM OF 2 - (2',4' - DINITROBENZYL) PYRIDINE [J].
TINLAND, B ;
DECORET, C .
TETRAHEDRON LETTERS, 1971, (27) :2467-&
[49]   Proton-transfer processes in well-defined media: Experimental investigation of photoinduced and thermal proton-transfer processes in single crystals of 2-(2,4-dinitrobenzyl)pyridine derivatives [J].
Scherl, M ;
Haarer, D ;
Fischer, J ;
DeCian, A ;
Lehn, JM ;
Eichen, Y .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (40) :16175-16186
[50]   Excited-state intramolecular proton transfer and spectroscopy of 2-(2'-hydroxyphenyl)benzoxazole in solid polymer matrices [J].
Tang, GQ ;
Shang, XM ;
Zhang, GL ;
Du, RJ ;
Chen, WJ .
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 1996, 17 (06) :906-910