Intramolecular proton transfer of a 2-(2′,4′-dinitrobenzyl)pyridine studied by femtosecond transient absorption spectroscopy

被引：12
作者：
Takeda, J [1 ]
Chung, DD [1 ]
Zhou, JP [1 ]
Nelson, KA [1 ]
机构：
[1] Yokohama Natl Univ, Fac Engn, Dept Phys, Yokohama, Kanagawa 2408501, Japan
来源：
CHEMICAL PHYSICS LETTERS | 1998年 / 290卷 / 4-6期
关键词：
D O I：
10.1016/S0009-2614(98)00506-5
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The photochromic intramolecular proton transfer in 2-(2',4'-dinitrobenzyl)pyridine was investigated by femtosecond pump-probe transient absorption spectroscopy. Three different transient absorption spectra were observed depending on the delay time between the pump and probe beams. Based on the analysis of the observed spectra, the reaction time of the intramolecular proton transfer of this material was estimated to be 320 similar to 500 fs. (C) 1998 Published by Elsevier Science B.V. AU rights reserved.
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页码：341 / 348
页数：8
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