Liquids intermediate between "molecular" and "ionic" liquids: Liquid Ion Pairs?

被引：227

作者：

Fraser, Kevin J.

Izgorodina, Ekaterina I.

Forsyth, Maria

Scott, Janet L.

MacFarlane, Douglas R. ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

[2] Monash Univ, Dept Mat Engn, Clayton, Vic 3800, Australia

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 37期

关键词：

D O I：

10.1039/b710014k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ionic liquids comprised of tetradecyltrihexyl- and tetrabutyl-phosphonium cations paired with chloride or sulfonyl amide anions exhibit properties that reflect strong ion association, including comparatively low viscosity as well as a degree of volatility, and hence exemplify an interesting intermediate state between true ionic and true molecular liquids.

引用

收藏

页码：3817 / 3819

页数：3

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