Liquids intermediate between "molecular" and "ionic" liquids: Liquid Ion Pairs?

被引：225
作者：
Fraser, Kevin J.
Izgorodina, Ekaterina I.
Forsyth, Maria
Scott, Janet L.
MacFarlane, Douglas R. [1 ]
机构：
[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
[2] Monash Univ, Dept Mat Engn, Clayton, Vic 3800, Australia
来源：
CHEMICAL COMMUNICATIONS | 2007年 / 37期
关键词：
D O I：
10.1039/b710014k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ionic liquids comprised of tetradecyltrihexyl- and tetrabutyl-phosphonium cations paired with chloride or sulfonyl amide anions exhibit properties that reflect strong ion association, including comparatively low viscosity as well as a degree of volatility, and hence exemplify an interesting intermediate state between true ionic and true molecular liquids.
引用
收藏
页码：3817 / 3819
页数：3
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