Synthesis of Polyaniline Coated Magnesium and Cobalt Oxide Nanoparticles through Eco-Friendly Approach and Their Application as Antifungal Agents

被引:7
作者
Manzoor, Suryyia [1 ]
Yasmin, Ghazala [1 ]
Raza, Nadeem [2 ]
Fernandez, Javier [3 ]
Atiq, Rashida [4 ]
Chohan, Sobia [4 ]
Iqbal, Ayesha [1 ]
Manzoor, Shamaila [5 ]
Malik, Barizah [6 ]
Winter, Franz [7 ]
Azam, Mudassar [7 ,8 ]
机构
[1] Bahauddin Zakariya Univ, Inst Chem Sci, Multan 60000, Pakistan
[2] Emerson Univ, Dept Chem, Multan 60000, Pakistan
[3] UCL, Dept Chem Engn, Torrington Pl, London WC1E 7JE, England
[4] Bahauddin Zakariya Univ, Dept Plant Pathol, Multan 60000, Pakistan
[5] Univ Florence, Dept Phys & Astron, Via Sansone 1, I-50019 Sesto Fiorentino, Italy
[6] Univ Punjab, Sch Biochem & Biotechnol, Lahore 54590, Pakistan
[7] TU WIEN, Inst Chem Environm & Biosci Engn, Getreidemarkt 9, A-1060 Vienna, Austria
[8] Univ Punjab, Inst Chem Engn & Technol, Lahore 54590, Pakistan
关键词
green synthesis; nanoparticles; PANI; Manilkara zapota leaves extract; Aspergillus niger; GREEN SYNTHESIS; NEEM LEAVES; ANTIBACTERIAL; NANOCOMPOSITES; EXTRACT; FACILE;
D O I
10.3390/polym13162669
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Plant-mediated synthesis of nanoparticles exhibits great potential to minimize the generation of chemical waste through the utilization of non-toxic precursors. In this research work, we report the synthesis of magnesium oxide (MgO) and cobalt oxide (Co3O4) nanoparticles through a green approach using Manilkara zapota leaves extract, their surface modification by polyaniline (PANI), and antifungal properties against Aspergillus niger. Textural and structural characterization of modified and unmodified metal oxide nanoparticles were evaluated using FT-IR, SEM, and XRD. The optimal conditions for inhibition of Aspergillus niger were achieved by varying nanoparticles' concentration and time exposure. Results demonstrate that PANI/MgO nanoparticles were superior in function relative to PANI/Co3O4 nanoparticles to control the growth rate of Aspergillus niger at optimal conditions (time exposure of 72 h and nanoparticles concentration of 24 mM). A percentage decrease of 73.2% and 65.1% in fungal growth was observed using PANI/MgO and PANI/Co3O4 nanoparticles, respectively, which was higher than the unmodified metal oxide nanoparticles (67.5% and 63.2%).
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页数:14
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