Emission spectrum of hot HDO below 4000 cm-1

被引：29
作者：
Janca, A
Tereszchuk, K
Bernath, PF
Zobov, NF
Shirin, SV
Polyansky, OL
Tennyson, J
机构：
[1] UCL, Dept Phys & Astron, London WC1E 6BT, England
[2] Univ Waterloo, Dept Chem, Waterloo, ON N2L 3G1, Canada
[3] Univ Arizona, Dept Chem, Tucson, AZ 85721 USA
[4] Russian Acad Sci, Inst Appl Phys, Nizhnii Novgorod 603950, Russia
来源：
JOURNAL OF MOLECULAR SPECTROSCOPY | 2003年 / 219卷 / 01期
基金：
美国国家航空航天局; 加拿大自然科学与工程研究理事会;
关键词：
water vapor; infrared spectrum; emission; line assignments; hot bands;
D O I：
10.1016/S0022-2852(03)00015-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
Fourier transform emission spectra were recorded using a mixture of H2O and D2O at a temperature of 1500degreesC. The spectra were recorded in three overlapping sections and cover the wavenumber range 1800-3932cm(-1). This spectrum is analyzed together with a previously reported one spanning the 380-2190cm(-1) range [Parekunnel et al., J. Mol. Spectrosc. 101 (2001) 28]. This analysis leads to 4409 newly assigned HDO emission lines. This work particularly extends data on the (200) and (120) states of HDO for which newly determined energy levels are presented. (C) 2003 Elsevier Science (USA). All rights reserved.
引用
收藏
页码：132 / 135
页数：4
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