Dissolution and Delignification of Bamboo Biomass Using Amino Acid-Based Ionic Liquid

被引:74
作者
Muhammad, Nawshad [1 ]
Man, Zakaria [1 ]
Bustam, Mohamad Azmi [1 ]
Mutalib, M. I. Abdul [1 ]
Wilfred, Cecilia D. [2 ]
Rafiq, Sikander [1 ]
机构
[1] Univ Teknol PETRONAS, Dept Chem Engn, PETRONAS Ion Liquid Ctr, Tronoh 31750, Perak, Malaysia
[2] Univ Teknol PETRONAS, Fundamental & Appl Sci Dept, Tronoh 31750, Perak, Malaysia
关键词
Bamboo biomass; Amino acid ionic liquid; Dissolution; Regeneration; Cellulose crystallinity; LIGNOCELLULOSIC MATERIALS; PRETREATMENT; WOOD; CELLULOSE; HYDROLYSIS; LIGNIN;
D O I
10.1007/s12010-011-9315-y
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
In the present work, the dissolution of bamboo biomass was tested using a number of ionic liquids synthesized in laboratory. It was observed that one of the synthesized amino acid-based ionic liquids, namely 1-ethyl-3-methylimidazolium glycinate, was capable of dissolving the biomass completely. The dissolved biomass was then regenerated using a reconstitute solvent (acetone/water) and was characterized using Fourier transform infrared spectroscopy, X-ray diffraction, and scanning electron microscopy. The results were compared to preconditioned bamboo biomass. The regenerated biomass was found to have a more homogenous macrostructure, which indicates that the crystalline form and structure of its cellulose has changed from type I (TM) to type I (TM) I (TM) during the dissolution and regeneration process.
引用
收藏
页码:998 / 1009
页数:12
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