Coupling of methane and ammonia by dinuclear bimetallic platinum-coinage-metal cations PtM+

被引：59

作者：

Koszinowski, K ^{[1
]}

Schröder, D ^{[1
]}

Schwarz, H ^{[1
]}

机构：

[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 01期

关键词：

C-H activation; cluster compounds; copper; gold; platinum; silver;

D O I：

10.1002/anie.200352817

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

And they all do it! Like PtAu+, the lighter dinuclear platinum-coinage-metal clusters PtCu+ and PtAg+ also mediate the C-N coupling of methane and ammonia. As the homonuclear clusters Pt2+, Cu2+, Ag2 +, and Au2+ are inactive (see scheme), the particular electronic situation of the bimetallic clusters appears to be crucial for the outcome of this intriguing reaction.

引用

页码：121 / 124

页数：4

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