A review on conductometric studies of electrolytes in mixed solvent systems to understand ion-ion and ion-solvent interactions

被引:0
作者
Talukdar, Malabika [1 ]
Singh, Sulochana [1 ]
Dehuri, Sujit K. [2 ]
机构
[1] SOA Deemed Be Univ, ITER, Dept Chem, Bhubaneswar, Odisha, India
[2] Vikram Deb Autonomous Coll, Dept Chem, Jeypore, Odisha, India
关键词
Solvation; association; conductance; electrolytes; physico-chemical properties; molecular interactions; PLUS WATER MIXTURES; ACETIC-ACID; LITHIUM BIS(FLUOROSULFONYL)IMIDE; SODIUM TETRAPHENYLBORATE; VISCOSITY MEASUREMENTS; CO(III) COMPLEXES; METHANOL MIXTURES; AQUEOUS-SOLUTIONS; CONDUCTANCE; ASSOCIATION;
D O I
10.33263/BRIAC103.355360
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The study of ion-solvent interaction is of much importance to investigate the nature of different solutions. Measurement of electrical conductivity and evaluation of physico-chemical properties, such as molar conductance, limiting molar conductance, ion-pair association, Walden product etc. shade light on different intermolecular interactions present in electrolyte solutions. Solvation properties can be varied by mixing two or more solvents. An extensive literature survey on conductometric studies has been carried out on different electrolytes dissolved in a wide range of mixed solvent systems. The reported results show that strong solute-solute, solute-solvent and solvent-solvent interactions are responsible for the physico-chemical behavior of a solution in mixed solvents.
引用
收藏
页码:5355 / 5360
页数:6
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