A review on conductometric studies of electrolytes in mixed solvent systems to understand ion-ion and ion-solvent interactions

被引：0

作者：

Talukdar, Malabika ^{[1
]}

Singh, Sulochana ^{[1
]}

Dehuri, Sujit K. ^{[2
]}

机构：

[1] SOA Deemed Be Univ, ITER, Dept Chem, Bhubaneswar, Odisha, India

[2] Vikram Deb Autonomous Coll, Dept Chem, Jeypore, Odisha, India

来源：

BIOINTERFACE RESEARCH IN APPLIED CHEMISTRY | 2020年 / 10卷 / 03期

关键词：

Solvation; association; conductance; electrolytes; physico-chemical properties; molecular interactions; PLUS WATER MIXTURES; ACETIC-ACID; LITHIUM BIS(FLUOROSULFONYL)IMIDE; SODIUM TETRAPHENYLBORATE; VISCOSITY MEASUREMENTS; CO(III) COMPLEXES; METHANOL MIXTURES; AQUEOUS-SOLUTIONS; CONDUCTANCE; ASSOCIATION;

D O I：

10.33263/BRIAC103.355360

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The study of ion-solvent interaction is of much importance to investigate the nature of different solutions. Measurement of electrical conductivity and evaluation of physico-chemical properties, such as molar conductance, limiting molar conductance, ion-pair association, Walden product etc. shade light on different intermolecular interactions present in electrolyte solutions. Solvation properties can be varied by mixing two or more solvents. An extensive literature survey on conductometric studies has been carried out on different electrolytes dissolved in a wide range of mixed solvent systems. The reported results show that strong solute-solute, solute-solvent and solvent-solvent interactions are responsible for the physico-chemical behavior of a solution in mixed solvents.

引用

页码：5355 / 5360

页数：6

共 60 条

[1] AN APPLICATION OF THE LEE-WHEATON CONDUCTANCE EQUATION TO MIXED (SYMMETRICAL AND ASYMMETRICAL) ELECTROLYTES IN METHANOL AT 25-DEGREES-C [J].

AKRAWI, BA ;

KHALIL, SM .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1992, 328 (1-2) :209-218

[2] Conductivity study with caffeinate anion - Caffeic acid and its sodium and potassium salts [J].

Apelblat, Alexander ;

Vranes, Milan ;

Gadzuric, Slobodan ;

Bester-Rogac, Marija .

JOURNAL OF MOLECULAR LIQUIDS, 2020, 300

[3] The universal curves of limiting conductances of 1:1 type electrolytes in alcohol-water-rich mixtures [J].

Apelblat, Alexander .

JOURNAL OF MOLECULAR LIQUIDS, 2010, 156 (01) :89-94

[4] Conductance studies of NaCl, KCl, NaBr, KBr, Bu4NBr, and NaBPh4 in water+2-methoxyethanol mixtures at 298.15 K [J].

Bald, Adam ;

Kinart, Zdzislaw ;

Wypych-Stasiewicz, Anna ;

Tomas, Renato .

JOURNAL OF MOLECULAR LIQUIDS, 2013, 182 :14-24

[5]

Barthel J. M., 1998, PHYS CHEM ELECTROLYT

[6] NOTE ON THE FUOSS-KRAUS EQUATION FOR THE CONDUCTANCE OF SOLUTIONS CONTAINING ION-TRIPLETS [J].

Baughan, E. C. .

JOURNAL OF PHYSICAL CHEMISTRY, 1960, 64 (12) :1951-1951

[7] Conductometric study of ion association of divalent symmetric electrolytes:: II.: MgSO4 in water plus 1,4-dioxane mixtures [J].

Bester-Rogac, M. ;

Hauptman, N. ;

Barthel, J. .

JOURNAL OF MOLECULAR LIQUIDS, 2007, 131 (SPEC. ISS.) :29-35

[8]

Bhat JI, 2006, INDIAN J CHEM A, V45, P1165

[9] Liquid electrolytes for lithium and lithium-ion batteries [J].

Blomgren, GE .

JOURNAL OF POWER SOURCES, 2003, 119 :326-329

[10] The Development and Future of Lithium Ion Batteries [J].

Blomgren, George E. .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2017, 164 (01) :A5019-A5025

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