UV-blue photoluminescence from close-packed SiC nanocrystal film

被引:20
作者
Fan, J. Y. [1 ,2 ]
Li, H. X. [3 ,4 ]
Wang, Q. J. [4 ]
Dai, D. J. [1 ]
Chu, P. K. [2 ]
机构
[1] Southeast Univ, Dept Phys, Nanjing 211189, Peoples R China
[2] City Univ Hong Kong, Dept Phys & Mat Sci, Kowloon, Hong Kong, Peoples R China
[3] Nanjing Univ Sci & Technol, Dept Appl Phys, Nanjing 210094, Peoples R China
[4] Nanjing Univ, Natl Lab Solid State Microstruct, Nanjing 210093, Peoples R China
基金
中国国家自然科学基金;
关键词
CHEMICAL-VAPOR-DEPOSITION; SILICON-CARBIDE; OPTICAL CHARACTERIZATION; 3C-SIC NANOCRYSTALS; POROUS SILICON; LUMINESCENCE; NANOSTRUCTURES; FABRICATION;
D O I
10.1063/1.3556657
中图分类号
O59 [应用物理学];
学科分类号
摘要
We observed stable photoluminescence from close-packed cubic SiC nanocrystals that are self-assembled into thin solid film. The peak wavelength shifts from blue to near UV with increasing excitation energy and follows well the quantum-confinement effect. The photoluminescence excitation spectrum indicates a 3.47 eV bandgap corresponding to a particle size of 2.3 nm. The nanocrystal film shows triple-exponential photoluminescence decay with lifetimes of 2.3, 8.5, and 36.9 ns. The results open the possibility of the solid state UV-blue light emitting by use of the SiC nanocrystals in photonics and photonics/electronics integration. (C) 2011 American Institute of Physics. [doi: 10.1063/1.3556657]
引用
收藏
页数:3
相关论文
共 30 条
[1]   Influence of quantum confinement on the critical points of the band structure of Si [J].
BenChorin, M ;
Averboukh, B ;
Kovalev, D ;
Polisski, G ;
Koch, F .
PHYSICAL REVIEW LETTERS, 1996, 77 (04) :763-766
[2]   Luminescence mechanisms in 6H-SiC nanocrystals [J].
Botsoa, J. ;
Bluet, J. M. ;
Lysenko, V. ;
Sfaxi, L. ;
Zakharko, Y. ;
Marty, O. ;
Guillot, G. .
PHYSICAL REVIEW B, 2009, 80 (15)
[3]   Linear electro-optical behavior of hybrid nanocomposites based on silicon carbide nanocrystals and polymer matrices [J].
Boucle, J. ;
Kassiba, A. ;
Makowska-Janusik, M. ;
Herlin-Boime, N. ;
Reynaud, C. ;
Desert, A. ;
Emery, J. ;
Bulou, A. ;
Sanetra, J. ;
Pud, A. A. ;
Kodjikian, S. .
PHYSICAL REVIEW B, 2006, 74 (20)
[4]   Nanosilicon photonics [J].
Daldosso, Nicola ;
Pavesi, Lorenzo .
LASER & PHOTONICS REVIEWS, 2009, 3 (06) :508-534
[5]  
Devaty RP, 1997, PHYS STATUS SOLIDI A, V162, P5, DOI 10.1002/1521-396X(199707)162:1<5::AID-PSSA5>3.0.CO
[6]  
2-J
[7]   Low-dimensional SiC nanostructures: Fabrication, luminescence, and electrical properties [J].
Fan, J. Y. ;
Wu, X. L. ;
Chu, Paul K. .
PROGRESS IN MATERIALS SCIENCE, 2006, 51 (08) :983-1031
[8]   Excitation and recombination photodynamics in colloidal cubic SiC nanocrystals [J].
Fan, J. Y. ;
Li, H. X. ;
Cui, W. N. ;
Dai, D. J. ;
Chu, P. K. .
APPLIED PHYSICS LETTERS, 2010, 97 (19)
[9]   Microstructure and infrared spectral properties of porous polycrystalline and nanocrystalline cubic silicon carbide [J].
Fan, J. Y. ;
Li, H. X. ;
Cui, W. N. .
APPLIED PHYSICS LETTERS, 2009, 95 (02)
[10]   3C-SiC nanocrystals as fluorescent biological labels [J].
Fan, Jiyang ;
Li, Hongxia ;
Iiang, Jiang ;
So, Leo K. Y. ;
Lam, Yun Wah ;
Chu, Paul K. .
SMALL, 2008, 4 (08) :1058-1062