Guilty as charged: non-innocent behavior by a pincer ligand featuring a central cationic phosphenium donor

被引:71
作者
Day, Gregory S. [1 ]
Pan, Baofei [1 ]
Kellenberger, Daniel L. [1 ]
Foxman, Bruce M. [1 ]
Thomas, Christine M. [1 ]
机构
[1] Brandeis Univ, Dept Chem, Waltham, MA 02454 USA
关键词
N-HETEROCYCLIC CARBENES; 14 ELEMENT LIGAND; COMPLEXES; IONS; COORDINATION; REACTIVITY; CHEMISTRY; CATALYSIS; ADDUCTS; ROUTE;
D O I
10.1039/c0cc05739h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis of a new pincer ligand containing a central cationic N-heterocyclic phosphenium donor is described. The electrophilic nature of this cationic ligand renders it non-innocent, and coordination of this ligand to a PtCl(2) fragment leads to chloride migration from Pt to the cationic phosphorus center.
引用
收藏
页码:3634 / 3636
页数:3
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