Guilty as charged: non-innocent behavior by a pincer ligand featuring a central cationic phosphenium donor

被引：71

作者：

Day, Gregory S. ^{[1
]}

Pan, Baofei ^{[1
]}

Kellenberger, Daniel L. ^{[1
]}

Foxman, Bruce M. ^{[1
]}

Thomas, Christine M. ^{[1
]}

机构：

[1] Brandeis Univ, Dept Chem, Waltham, MA 02454 USA

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 12期

关键词：

N-HETEROCYCLIC CARBENES; 14 ELEMENT LIGAND; COMPLEXES; IONS; COORDINATION; REACTIVITY; CHEMISTRY; CATALYSIS; ADDUCTS; ROUTE;

D O I：

10.1039/c0cc05739h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of a new pincer ligand containing a central cationic N-heterocyclic phosphenium donor is described. The electrophilic nature of this cationic ligand renders it non-innocent, and coordination of this ligand to a PtCl(2) fragment leads to chloride migration from Pt to the cationic phosphorus center.

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收藏

页码：3634 / 3636

页数：3

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