Highly stereoselective and catalyst-free synthesis of annulated tetrahydropyridines by intramolecular imino-Diels-Alder reaction under microwave irradiation in water
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作者:
Lezana, Nicolas
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Univ Chile, Fac Sci, Dept Chem, Las Palmeras 3425, Santiago 7800024, ChileUniv Chile, Fac Sci, Dept Chem, Las Palmeras 3425, Santiago 7800024, Chile
Lezana, Nicolas
[1
]
Matus-Perez, Massiel
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Univ Chile, Fac Sci, Dept Chem, Las Palmeras 3425, Santiago 7800024, ChileUniv Chile, Fac Sci, Dept Chem, Las Palmeras 3425, Santiago 7800024, Chile
Matus-Perez, Massiel
[1
]
Galdamez, Antonio
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Univ Chile, Fac Sci, Dept Chem, Las Palmeras 3425, Santiago 7800024, ChileUniv Chile, Fac Sci, Dept Chem, Las Palmeras 3425, Santiago 7800024, Chile
Galdamez, Antonio
[1
]
Luehr, Susan
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Univ Santiago Chile, Fac Chem & Biol, Dept Mat Sci, Av Libertador Bernardo OHiggins 3363, Santiago 9170022, ChileUniv Chile, Fac Sci, Dept Chem, Las Palmeras 3425, Santiago 7800024, Chile
Luehr, Susan
[2
]
Vilches-Herrer, Marcelo
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Univ Chile, Fac Sci, Dept Chem, Las Palmeras 3425, Santiago 7800024, ChileUniv Chile, Fac Sci, Dept Chem, Las Palmeras 3425, Santiago 7800024, Chile
Vilches-Herrer, Marcelo
[1
]
机构:
[1] Univ Chile, Fac Sci, Dept Chem, Las Palmeras 3425, Santiago 7800024, Chile
[2] Univ Santiago Chile, Fac Chem & Biol, Dept Mat Sci, Av Libertador Bernardo OHiggins 3363, Santiago 9170022, Chile
A microwave-assisted method for the synthesis of tetracyclic tetra-hydropyridines via an intramolecular imino-Diels-Alder reaction in water is reported. The reaction proceeds under catalyst-free conditions and shows excellent stereoselectivity.