Magnetic nanoparticle-supported tetrazole-functionalized palladium catalyst: synthesis, DFT study and application for Sonogashira and Heck cross-coupling reactions

被引：22

作者：

Elhampour, Ali ^{[1
]}

Nemati, Firouzeh ^{[1
]}

Nahzomi, Hossein Taherpour ^{[2
]}

Mohagheghi, Vahid ^{[1
]}

机构：

[1] Semnan Univ, Dept Chem, Semnan 3513119111, Iran

[2] Payame Noor Univ, Dept Chem, Tehran, Iran

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2017年 / 43卷 / 11期

关键词：

Nano-magnetic catalyst; Aminobenzonitrile; Azidopropyltriethoxysilane; Tetrazole; DFT study; CORE-SHELL COMPOSITE; ACIDIC IONIC LIQUID; FREE N-ARYLATION; SUZUKI-MIYAURA; RECYCLABLE CATALYST; EFFICIENT CATALYST; HETEROGENEOUS CATALYST; RECOVERABLE CATALYST; REUSABLE CATALYST; HIGHLY EFFICIENT;

D O I：

10.1007/s11164-017-3018-0

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel magnetic catalyst-immobilized nano-palladium was efficiently prepared via a (2 + 3) cycloaddition pathway and characterized with different analyses, including FT-IR, FE-SEM, EDS, XRD, TEM and VSM methods. Also, topological and NBO analysis of a simple model of the catalyst with the M06/6-311 g(d,p)-LANL2DZ model chemistry have been introduced. In addition, the catalytic pursuit of this novel magnetic nanocatalyst was successfully evaluated in Sonogashira and Heck cross-coupling reactions. Furthermore, the catalyst could be easily separated by a conventional method using a permanent magnet and reused repeatedly in the model reaction without noteworthy loss of its catalytic activity. [GRAPHICS] .

引用

页码：6737 / 6761

页数：25

共 88 条

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