Modifying Chemical Landscapes by Coupling to Vacuum Fields

被引：743

作者：

Hutchison, James A. ^{[1
,2
]}

Schwartz, Tal ^{[1
,2
]}

Genet, Cyriaque ^{[1
,2
]}

Devaux, Eloise ^{[1
,2
]}

Ebbesen, Thomas W. ^{[1
,2
]}

机构：

[1] Univ Strasbourg, ISIS, Strasbourg, France

[2] CNRS, UMR 7006, Strasbourg, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 07期

基金：

欧洲研究理事会;

关键词：

cavity quantum electrodynamics; energy landscape; hybrid light-matter states; strong coupling; vacuum field; SINGLE QUANTUM-DOT; SEMICONDUCTOR MICROCAVITY; SPIROPYRAN; DYNAMICS; CAVITY; PHOTOCHROMISM; STATES;

D O I：

10.1002/anie.201107033

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electromagnetic vacuum fields are omnipresent in our universe, inducing many events such as spontaneous emission, Lamb shift, and Van der Waals forces. As demonstrated here, a chemical reaction can be influenced by strongly coupling the energy landscape governing the reaction pathway to vacuum fields in an optical cavity (see picture; MC=merocyanine). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1592 / 1596

页数：5

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