Zn doping-induced enhanced dielectric response of quantum paraelectric SrTiO3

被引:6
作者
Guo, Y. Y. [1 ]
Guo, Y. J. [1 ,2 ]
Liu, J-M. [1 ,3 ]
机构
[1] Nanjing Univ, Lab Solid State Microstruct, Nanjing 210093, Jiangsu, Peoples R China
[2] Jiangsu Inst Educ, Dept Phys, Nanjing 210013, Jiangsu, Peoples R China
[3] Chinese Acad Sci, Int Ctr Mat Phys, Shenyang, Peoples R China
关键词
STRONTIUM-TITANATE; FERROELECTRICITY; TRANSITION; BEHAVIOR;
D O I
10.1063/1.3703070
中图分类号
O59 [应用物理学];
学科分类号
摘要
The dielectric and ferroelectric behaviors of Zn2+-doped SrTiO3 (STO-Zn) have been investigated to explore the effects of Zn-doping on quantum fluctuations and ferroelectric instability. Structurally, the smaller Zn2+ ions occupy the Sr2+ sites at low substitution level up to 0.9% and an over-substitution may lead to impurity phase. It is found that no ferroelectric or relaxor-like anomaly emerges, while significantly enhanced dielectric constant and broad dielectric plateau are identified upon the substitution. These phenomena observed in Zn2+-doped STO are slightly different from well investigated Ca2+-doped STO and additional mechanism besides the off-centrality of Zn2+ ions at Sr2+ sites is possible. The transverse-field Ising model is consulted to explain self-consistently the observed effects. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.3703070]
引用
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页数:4
相关论文
共 26 条
[1]   DIELECTRIC CONSTANT IN PEROVSKITE TYPE CRYSTALS [J].
BARRETT, JH .
PHYSICAL REVIEW, 1952, 86 (01) :118-120
[2]   SR1-XCAXTIO3 - AN XY QUANTUM FERROELECTRIC WITH TRANSITION TO RANDOMNESS [J].
BEDNORZ, JG ;
MULLER, KA .
PHYSICAL REVIEW LETTERS, 1984, 52 (25) :2289-2292
[3]   Frustration of tilts and A-site driven ferroelectricity in KNbO3-LiNbO3 alloys [J].
Bilc, DI ;
Singh, DJ .
PHYSICAL REVIEW LETTERS, 2006, 96 (14)
[4]   STRESS INDUCED FERROELECTRICITY IN SRTIO3 [J].
BURKE, WJ ;
PRESSLEY, RJ .
SOLID STATE COMMUNICATIONS, 1971, 9 (03) :191-&
[5]   ELECTRIC-FIELD-INDUCED RAMAN SCATTERING IN SRTIO3 AND KTAO3 [J].
FLEURY, PA ;
WORLOCK, JM .
PHYSICAL REVIEW, 1968, 174 (02) :613-&
[6]   Polar clusters in impurity-doped quantum paraelectric K1-xLixTaO3 [J].
Geneste, Gregory ;
Kiat, Jean-Michel ;
Yokota, Hiroko ;
Uesu, Yoshiaki ;
Porcher, Florence .
PHYSICAL REVIEW B, 2010, 81 (14)
[7]   Giant piezoelectric effect in strontium titanate at cryogenic temperatures [J].
Grupp, DE ;
Goldman, AM .
SCIENCE, 1997, 276 (5311) :392-394
[8]   Double-impurity doping-induced quantum critical behaviors in Sr1-xBaxTi1-yRuyO3 [J].
Guo, Y. J. ;
Wei, T. ;
Zhu, C. ;
Wang, K. F. ;
Gao, X. S. ;
Guan, Y. Q. ;
Liu, J. -M. .
JOURNAL OF APPLIED PHYSICS, 2010, 107 (07)
[9]   Room-temperature ferroelectricity in strained SrTiO3 [J].
Haeni, JH ;
Irvin, P ;
Chang, W ;
Uecker, R ;
Reiche, P ;
Li, YL ;
Choudhury, S ;
Tian, W ;
Hawley, ME ;
Craigo, B ;
Tagantsev, AK ;
Pan, XQ ;
Streiffer, SK ;
Chen, LQ ;
Kirchoefer, SW ;
Levy, J ;
Schlom, DG .
NATURE, 2004, 430 (7001) :758-761
[10]   ORIENTATIONAL GLASSES [J].
HOCHLI, UT ;
KNORR, K ;
LOIDL, A .
ADVANCES IN PHYSICS, 1990, 39 (05) :405-615