Carbon dots as new eco-friendly and effective corrosion inhibitor

被引:151
作者
Cui, Mingjun [1 ,2 ]
Ren, Siming [1 ,2 ]
Xue, Qunji [1 ]
Zhao, Haichao [1 ]
Wang, Liping [1 ]
机构
[1] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Zhejiang Key Lab Marine Mat & Protect Technol, Key Lab Marine Mat & Related Technol, Ningbo 315201, Zhejiang, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100039, Peoples R China
关键词
Q235 carbon steel; Carbon dot; Eco-friendly inhibitor; Electrochemical measurements; 1 M HCL; MILD-STEEL; ACIDIC-SOLUTION; IONIC LIQUIDS; GREEN; ADSORPTION; DERIVATIVES; EFFICIENCY; NANODOTS; EXTRACT;
D O I
10.1016/j.jallcom.2017.08.027
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Inspired by the high water solubility and low cytotoxicity of N doped carbon dots (CDs) prepared by using antibiotic aminosalicylic acid (ASA) as precursor, we anticipate that these CDs may possess an excellent protective ability to inhibit the corrosion of carbon steel in aggressive solutions owing to its special structure. Therefore, the investigation on the inhibiting effect of CDs as eco-friendly corrosion inhibitor for Q235 carbon steel corrosion in 1 M HCl solution is first reported. Electrochemical techniques, weight loss, morphological and elements characterization are combined to investigate the inhibiting effect and corrosion mechanism. The results show that corrosion of Q235 carbon steel in 1 M HCl solution is significantly inhibited by the addition of CDs, which is attributed to the formation of CDs adsorption film, and the adsorption of CDs obeys a Langmuir adsorption isotherm.Besides, the protection efficiency increases with increasing concentration of CDs and prolonged immersion time, and reaches equilibrium eventually. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:680 / 692
页数:13
相关论文
共 42 条
[1]   Factors affecting the corrosion behaviour of aluminium in acid solutions. I. Nitrogen and/or sulphur-containing organic compounds as corrosion inhibitors for Al in HCl solutions [J].
Abd El Haleem, S. M. ;
Abd El Wanees, S. ;
Abd El Aal, E. E. ;
Farouk, A. .
CORROSION SCIENCE, 2013, 68 :1-13
[2]   Thermodynamic, electrochemical and quantum chemical investigation of some Schiff bases as corrosion inhibitors for mild steel in hydrochloric acid solutions [J].
Ahamad, Ishtiaque ;
Prasad, Rajendra ;
Quraishi, M. A. .
CORROSION SCIENCE, 2010, 52 (03) :933-942
[3]   Testing validity of the Tafel extrapolation method for monitoring corrosion of cold rolled steel in HCl solutions - Experimental and theoretical studies [J].
Amin, Mohammed A. ;
Khaled, K. F. ;
Fadl-Allah, Sahar A. .
CORROSION SCIENCE, 2010, 52 (01) :140-151
[4]  
[Anonymous], 2008, MATER PERFORMANCE, V47, P80
[5]   Schiff's base of pyridyl substituted triazoles as new and effective corrosion inhibitors for mild steel in hydrochloric acid solution [J].
Ansari, K. R. ;
Quraishi, M. A. ;
Singh, Ambrish .
CORROSION SCIENCE, 2014, 79 :5-15
[6]   Weight Loss, Electrochemical, Quantum Chemical Calculation, and Molecular Dynamics Simulation Studies on 2-(Benzylthio)-1,4,5-triphenyl-1H-imidazole as an Inhibitor for Carbon Steel Corrosion in Hydrochloric Acid [J].
Ben Hmamou, Dris ;
Salghi, Rachid ;
Zarrouk, Abdelkader ;
Aouad, Mohamed Reda ;
Benali, Omar ;
Zarrok, Hassan ;
Messali, Mousslim ;
Hammouti, Belkheir ;
Kabanda, Mwadham M. ;
Bouachrine, Mohammed ;
Ebenso, Eno E. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2013, 52 (40) :14315-14327
[7]   Corrosion resistance of carbon steel in weak acid solutions in the presence of L-histidine as corrosion inhibitor [J].
Bobina, Marian ;
Kellenberger, Andrea ;
Millet, Jean-Pierre ;
Muntean, Cornelia ;
Vaszilcsin, Nicolae .
CORROSION SCIENCE, 2013, 69 :389-395
[8]   Corrosion inhibition of mild steel by two new S-heterocyclic compounds in 1 M HCl: Experimental and computational study [J].
Daoud, Djamel ;
Douadi, Tahar ;
Hamani, Hanane ;
Chafaa, Salah ;
Al-Noaimi, Mousa .
CORROSION SCIENCE, 2015, 94 :21-37
[9]   Investigation of corrosion inhibition effect of 3-[(2-hydroxy-benzylidene)-amino]-2-thioxo-thiazolidin-4-one on corrosion of mild steel in the acidic medium [J].
Doner, Ali ;
Sahin, Ece Altunbas ;
Kardas, Gulfeza ;
Serindag, Osman .
CORROSION SCIENCE, 2013, 66 :278-284
[10]   Evaluation of Thymus vulgaris plant extract as an eco-friendly corrosion inhibitor for stainless steel 304 in acidic solution by means of electrochemical impedance spectroscopy, electrochemical noise analysis and density functional theory [J].
Ehsani, A. ;
Mahjani, M. G. ;
Hosseini, M. ;
Safari, R. ;
Moshrefi, R. ;
Shiri, H. Mohammad .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2017, 490 :444-451