The designed assembly of augmented diamond networks from predetermined pentanuclear tetrahedral units

被引：125
作者：
Bai, Yue-Ling
Tao, Jun [1 ]
Huang, Rong-Bin
Zheng, Lan-Sun
机构：
[1] Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 29期
关键词：
magnetic properties; mass spectrometry; materials science; organic-inorganic hybrid composites; radical ions;
D O I：
10.1002/anie.200800403
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Step by step: Pentanuclear clusters (see picture) are synthesized as building units for the construction of three-dimensional, diamondlike networks. The ESI mass spectra of these clusters reveal that the pentanuclear units maintain their structural integrity before condensing into frameworks, thereby allowing a successful step-by-step assembly. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：5344 / 5347
页数：4
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