Nickel ferrite bearing nitrogen-doped mesoporous carbon as efficient adsorbent for the removal of highly toxic metal ion from aqueous medium

被引:420
作者
Naushad, Mu. [1 ]
Ahamad, Tansir [1 ]
Al-Maswari, Basheer M. [1 ]
Alqadami, Ayoub Abdullah [1 ]
Alshehri, Saad M. [1 ]
机构
[1] King Saud Univ, Coll Sci, Dept Chem, Bldg 5, Riyadh, Saudi Arabia
关键词
Nickel ferrite; Nitrogen-doped carbon; Mesoporous; Toxic metal; Adsorption; RESPONSE-SURFACE METHODOLOGY; EVOLVED GAS-ANALYSIS; ACTIVATED CARBON; HEAVY-METALS; ADSORPTION PARAMETERS; NANOCOMPOSITE; WATER; PERFORMANCE; ISOTHERMS; RECOVERY;
D O I
10.1016/j.cej.2017.08.079
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Nickel ferrite bearing nitrogen-doped mesoporous carbon (NiFe2O4-NC) was prepared using polymer bimetal complexes and used for the removal of Hg2+ from aqueous medium. The nanocomposite was characterized using several analytical techniques such as SEM, TEM, FTIR, Raman, TGA/DTA, XRD, VSM, XPS and BET. The adsorption behavior of NiFe2O4-NC nanocomposites was investigated via adsorption kinetics, isotherms and thermodynamic. The adsorption isotherm could be well described with Langmuir model, with the maximum adsorption capacity of 476.2 mg g(-1) at 25 degrees C. The desorption results showed the best recovery of Hg2+ metal ion using 0.01 M HCl. The remarkable adsorption properties are mainly attributed to the synergetic chemical coupling effects between NiFe2O4 nanoparticles and nitrogen doped graphitized carbon. The presented cost-effective strategy is developed to prepared NiFe2O4 nanocrystals embedded in nitrogen-doped graphitized carbon matrix using a single source precursor offers prospects in developing highly effective magnetic adsorbent for removal of toxic pollutant form contaminated water.
引用
收藏
页码:1351 / 1360
页数:10
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