共 64 条
Nickel ferrite bearing nitrogen-doped mesoporous carbon as efficient adsorbent for the removal of highly toxic metal ion from aqueous medium
被引:431
作者:
Naushad, Mu.
[1
]
Ahamad, Tansir
[1
]
Al-Maswari, Basheer M.
[1
]
Alqadami, Ayoub Abdullah
[1
]
Alshehri, Saad M.
[1
]
机构:
[1] King Saud Univ, Coll Sci, Dept Chem, Bldg 5, Riyadh, Saudi Arabia
关键词:
Nickel ferrite;
Nitrogen-doped carbon;
Mesoporous;
Toxic metal;
Adsorption;
RESPONSE-SURFACE METHODOLOGY;
EVOLVED GAS-ANALYSIS;
ACTIVATED CARBON;
HEAVY-METALS;
ADSORPTION PARAMETERS;
NANOCOMPOSITE;
WATER;
PERFORMANCE;
ISOTHERMS;
RECOVERY;
D O I:
10.1016/j.cej.2017.08.079
中图分类号:
X [环境科学、安全科学];
学科分类号:
08 ;
0830 ;
摘要:
Nickel ferrite bearing nitrogen-doped mesoporous carbon (NiFe2O4-NC) was prepared using polymer bimetal complexes and used for the removal of Hg2+ from aqueous medium. The nanocomposite was characterized using several analytical techniques such as SEM, TEM, FTIR, Raman, TGA/DTA, XRD, VSM, XPS and BET. The adsorption behavior of NiFe2O4-NC nanocomposites was investigated via adsorption kinetics, isotherms and thermodynamic. The adsorption isotherm could be well described with Langmuir model, with the maximum adsorption capacity of 476.2 mg g(-1) at 25 degrees C. The desorption results showed the best recovery of Hg2+ metal ion using 0.01 M HCl. The remarkable adsorption properties are mainly attributed to the synergetic chemical coupling effects between NiFe2O4 nanoparticles and nitrogen doped graphitized carbon. The presented cost-effective strategy is developed to prepared NiFe2O4 nanocrystals embedded in nitrogen-doped graphitized carbon matrix using a single source precursor offers prospects in developing highly effective magnetic adsorbent for removal of toxic pollutant form contaminated water.
引用
收藏
页码:1351 / 1360
页数:10
相关论文