Poly[[[μ2-1,1′-(butane-1,4-diyl)bis(1H-imidazole)-κ2N3:N3′](μ2-2,6-dimethylpyridine-3,5-dicarboxylato-κ2O3:O5)zinc] dihydrate]

被引：0

作者：

Yue, Yu-Mei ^{[1
]}

Qian, Lei ^{[2
]}

Zhu, Zheng-Hao ^{[3
]}

Wang, Cheng ^{[4
]}

Gao, Ting ^{[4
]}

机构：

[1] Heilongjiang Univ, Pesticide Engn Res Ctr Heilongjiang Prov, Harbin 150080, Peoples R China

[2] Daqing Oil Field Water Supply Co, Inst Source Water Res, Daqing 163458, Peoples R China

[3] Dionex China Ltd, Dept Serv, Beijing 100029, Peoples R China

[4] Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

关键词：

COORDINATION POLYMERS; LIGANDS;

D O I：

10.1107/S1600536811039481

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title coordination polymer, {[Zn(C9H7NO4)(C10H14N4)]center dot 2H(2)O}(n), the Zn-II ion displays a distorted tetrahedral geometry with two imidazole N atoms from two 1,1'-(butane-1,4-diyl)bis(imidazole) (bbi) ligands and two carboxylate O atoms from two 2,6-dimethylpyridine-3,5-dicarboxylate (dpdc) ligands. The bbi and dpdc ligands bridge the Zn-II ions, forming layers parallel to (011). O-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds and pi-pi interactions between the imidazole rings [centroid-centroid distance = 3.807 (5) angstrom] connect the layers. Two of the three uncoordinated water molecules are disordered, each over two 0.25-occupancy positions.

引用

页码：M1471 / U1538

页数：11

共 12 条

[1]

[Anonymous], 2007, SMART SAINT

[2]

Brandenburg K., 1999, DIAMOND

[3] Synthesis and characterization of two temperature-dependent copper(II) complexes based on 2,6-dimethylpyridine-3,5-dicarboxylate [J].

Chen, Cui-Ling ;

Zou, Ye ;

Qiu, Ping ;

Wen, Yu-Hua ;

Li, Jun-Yong ;

Hong, Ze-Hong ;

Lin, Xiao-Ming ;

Xu, An-Xwu ;

Cai, Yue-Peng .

JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (15) :2480-2489

[4] ON ENANTIOMORPH-POLARITY ESTIMATION [J].

FLACK, HD .

ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881

[5]

Huang KL, 2008, CHINESE J STRUC CHEM, V27, P1499

[6] Self-Assembly of 2D→2D Interpenetrating Coordination Polymers Showing Polyrotaxane- and Polycatenane-like Various Ligands on Topological Structural Motifs: Influence of Diversity [J].

Lan, Ya-Qian ;

Li, Shun-Li ;

Qin, Jun-Sheng ;

Du, Dong-Ying ;

Wang, Xin-Long ;

Su, Zhong-Min ;

Fu, Qiang .

INORGANIC CHEMISTRY, 2008, 47 (22) :10600-10610

[7]

Sheldrick G.M., 1996, SADABS

[8] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

[9] A novel heterostranded double-helical coordination polymer with chiral channels emitting blue fluorescence [J].

Tian, Zhengfang ;

Duan, Haibao ;

Xuan, Fang ;

Ren, Xiaoming .

INORGANIC CHEMISTRY COMMUNICATIONS, 2009, 12 (05) :417-419

[10] Poly[bis(μ-2,6-dimethylpyridinium-3,5-dicarboxylato-κ2O3:O5)copper(II)] [J].

Zhang, Hong-Kun ;

Du, Yu-Hong ;

Jiang, Tao ;

Li, Bai-Yan ;

Hou, Guang-Feng .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 :M1510-U277

← 1 2 →