Synthesis of Adamantane-Based Betaine and Quaternary Ammonium Surfactants

被引：0

作者：

Cai, Lu ^{[1
]}

Guo, Jianwei ^{[1
]}

Liu, Sa ^{[2
]}

Zhu, Lejie ^{[1
]}

Guan, Nianyun ^{[1
]}

Cui, Yingde ^{[1
]}

Sun, Baoxing ^{[3
]}

机构：

[1] Guangdong Univ Technol, Fac Chem Engn & Light Ind, Guangzhou 510006, Guangdong, Peoples R China

[2] S China Univ Technol, Coll Mat Sci & Engn, Guangzhou 510640, Peoples R China

[3] Guangzhou Rui Yang Surfactant Ltd, Guangzhou 511400, Guangdong, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 31卷 / 08期

关键词：

adamantane; quaternary ammonium; surfactant; synthesis;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-(1-Adamantyl)-N,N-dimethylamine was synthesized by Eschweiler-Clarke methylation reaction of 1-adamantine and formaldehyde in presence of excess formic acid firstly. Then five adamantane-based surfactants, including N-(1-adamantyl)-N,N-dimethyl-betaine, N-(1-adamantyl)-N,N-dimethylbutyl-1-ammonium bromide, N-(1-adamantyl)-N,N-dimethyloctyl-1-ammonium bromide, N-(1-adamantyl)-N,N-dimethyldodecyl-1-ammonium bromide and N-(1-adamantyl)-N,N-dimethyl-hexadecyl-1-ammonium bromide were prepared via quaternarization reactions of N-(1-adamantyl)-N,N-dimethylamine with the sodium chloroacetate, 1-bromobutane, 1-bromooctane, 1-bromododecane and 1-bromohexadecane, respectively. The structures of products were identified by elemental analysis, IR, (HNMR)-H-1, etc.

引用

页码：1290 / 1294

页数：5

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