One-pot Synthesis of 4-Aryl-NH-1,2,3-triazoles in Presence of Fe3O4@SiO2@Propyl-HMTA as a New Basic Catalyst

被引：11
|
作者：
Mirzaei-Mosbat, Maryam [1 ]
Ghorbani-Vaghei, Ramin [1 ]
Sarmast, Narges [1 ]
机构：
[1] Bu Ali Sina Univ, Dept Organ Chem, Fac Chem, Hamadan 6517838683, Iran
来源：
CHEMISTRYSELECT | 2019年 / 4卷 / 05期
关键词：
Catalyst; Cycloaddition; Henry Reaction; Synthesis; Triazoles; IONIC LIQUIDS; MAGNETIC NANOPARTICLES; SILICA-NANOPARTICLES; KINETIC RESOLUTION; DICHLORIDE SILICA; HIGHLY EFFICIENT; COMPLEX; WATER; PHASE;
D O I：
10.1002/slct.201803545
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this paper, hexamethylenetetramine-functionalized magnetic Fe3O4 nanoparticles (Fe3O4@SiO2@Propyl-HMTA) catalyst was prepared and utilized for the synthesis of 4-aryl-NH-1,2,3-triazole derivatives. Also, the interaction between aldehyde, nitromethane, and sodium azide was investigated within the synthesis route. Henry Reaction between the aldehyde and nitromethane created an intermediate that was immediately attacked by N-3(-). As a result of this attack, 4-aryl-NH-1,2,3-triazole was generated through an in situ [3 + 2] cycloaddition.
引用
收藏
页码：1731 / 1737
页数：7
相关论文
共 50 条
  • [1] 1, 4-Diazabicyclo[2.2.2]octane-sulfonic acid immobilized on magnetic Fe3O4@SiO2 nanoparticles: a novel and recyclable catalyst for the one-pot synthesis of 4-aryl-NH-1, 2, 3-triazoles
    Nejad, Masoumeh Jadidi
    Pazoki, Farzane
    Bagheri, Sepideh
    Yazdani, Elahe
    Heydari, Akbar
    JOURNAL OF CHEMICAL SCIENCES, 2020, 132 (01)
  • [2] 1, 4-Diazabicyclo[2.2.2]octane-sulfonic acid immobilized on magnetic Fe3O4@SiO2 nanoparticles: a novel and recyclable catalyst for the one-pot synthesis of 4-aryl-NH-1, 2, 3-triazoles
    MASOUMEH JADIDI NEJAD
    FARZANE PAZOKI
    SEPIDEH BAGHERI
    ELAHE YAZDANI
    AKBAR HEYDARI
    Journal of Chemical Sciences, 2020, 132
  • [3] Fe3O4@SiO2@Propyl-ANDSA: as a new catalyst for one-pot synthesis of 4H-chromene
    Sanati, Hassan
    Karamshahi, Zahra
    Ghorbani-Vaghei, Ramin
    RESEARCH ON CHEMICAL INTERMEDIATES, 2019, 45 (02) : 709 - 726
  • [4] A solvent-free synthesis of 4-aryl-NH-1,2,3-triazoles from ketones utilizing diphenyl phosphorazidate
    Ishihara, Kotaro
    Ishihara, Kazuki
    Kato, Yamato
    Shibuya, Shota
    Shioiri, Takayuki
    Matsugi, Masato
    SYNTHETIC COMMUNICATIONS, 2022, 52 (9-10) : 1326 - 1335
  • [5] Fe3O4@SiO2@Propyl–ANDSA: as a new catalyst for one-pot synthesis of 4H-chromene
    Hassan Sanati
    Zahra Karamshahi
    Ramin Ghorbani-Vaghei
    Research on Chemical Intermediates, 2019, 45 : 709 - 726
  • [6] Fe3O4@SiO2-NH2 Nanocomposite as a Robust and Effective Catalyst for the One-pot Synthesis of Polysubstituted Dihydropyridines
    Ghasemzadeh, Mohammad Ali
    Abdollahi-Basir, Mohammad Hossein
    ACTA CHIMICA SLOVENICA, 2016, 63 (03) : 627 - 637
  • [7] Folic-Acid-Functionalized Magnetic Nanoparticles as Green and Magnetic Recyclable Catalyst for the Synthesis of 4-Aryl-NH-1,2,3-triazoles in a Green Media
    Bagheri, Sepideh
    Nejad, Masoumeh Jadidi
    Pazoki, Farzane
    Miraki, Maryam Kazemi
    Heydari, Akbar
    CHEMISTRYSELECT, 2019, 4 (40): : 11930 - 11935
  • [8] HFIP-Mediated Synthesis of 4-Aryl-NH-1,2,3-Triazoles and 1,5-Disubstituted 1,2,3-Triazolyl Glycoconjugates
    Jaiswal, Manoj K.
    Yadav, Mangal S.
    Maurya, Shristy
    Ansari, Danish
    Tiwari, Vinod K.
    JOURNAL OF ORGANIC CHEMISTRY, 2024, 89 (23) : 17213 - 17227
  • [9] Facile Synthesis of 1,3,5-Triarylbenzenes and 4-Aryl-NH-1,2,3-Triazoles Using Mesoporous Pd-MCM-41 as Reusable Catalyst
    Saha, Arijit
    Wu, Chia-Ming
    Peng, Rui
    Koodali, Ranjit
    Banerjee, Subhash
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2019, 2019 (01) : 104 - 111
  • [10] Fe3O4@SiO2@propyl-ANDSA: A new catalyst for the synthesis of tetrazoloquinazolines
    Ghorbani-Vaghei, Ramin
    Alavinia, Sedigheh
    Sarmast, Narges
    APPLIED ORGANOMETALLIC CHEMISTRY, 2018, 32 (02)
12345