A vacuum ultraviolet photoionization study on the thermal decomposition of ammonium perchlorate

被引：21

作者：

Gobi, Sandor ^{[1
,2
]}

Zhao, Long ^{[1
,2
]}

Xu, Bo ^{[3
]}

Ablikim, Utuq ^{[3
]}

Ahmed, Musahid ^{[3
]}

Kaiser, Ralf I. ^{[1
,2
]}

机构：

[1] Univ Hawaii Manoa, Dept Chem, Honolulu, HI 96822 USA

[2] Univ Hawaii Manoa, WM Keck Lab Astrochem, Honolulu, HI 96822 USA

[3] Lawrence Berkeley Natl Lab, Chem Sci Div, Berkeley, CA 94720 USA

来源：

CHEMICAL PHYSICS LETTERS | 2018年 / 691卷

关键词：

AB-INITIO; CLOX REACTIONS; RATE-CONSTANT; SPECTROSCOPY; PREDICTION; COMBUSTION; MECHANISM; KINETICS; MS;

D O I：

10.1016/j.cplett.2017.11.026

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Pyrolysis products of ammonium perchlorate (NH4ClO4) at 483 K were monitored on line and in situ via single photon photoionization reflectron time-of-flight spectrometry (PI-ReTOF-MS) in the photon energy range of 9.00-17.50 eV. The photoionization efficiency curves (PIE) of the subliming product molecules were collected and allowed for detection of three class of products containing chlorine, nitrogen, and oxygen including atoms and free radicals. These results suggest a new insight into possible low-temperature decomposition pathways of NH4ClO4. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：250 / 257

页数：8

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