Solid-state asymmetric reduction of (S)-1,1′-bi-2-naphthol-acetylferrocene molecular compound with sodium borohydride

被引：0

作者：

Du, HF

Ding, KL ^{[1
]}

Meng, JB

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2001年 / 19卷 / 07期

关键词：

1,1 '-bi-2-naphthol; acetylferrocene; molecular crystal; asymmetric reduction; solid-state reaction; sodium borohydride;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel molecular crystal formed between enantiopure 1,1 ' -bi-2-naphthol and acetylferrocene has been prepared and characterized in this communication. The examination on its reduction with sodium borohydride showed that the asymmetric induction was observed in the solid state but not in the solution phase. The asymmetric induction in the solid-state reduction may be attributed to the chiral microenvironment of molecular crystal.

引用

页码：716 / 718

页数：3

共 14 条

[1] CHIRAL SYNTHESIS VIA ORGANOBORANES .14. SELECTIVE REDUCTIONS .41. DIISOPINOCAMPHEYLCHLOROBORANE, AN EXCEPTIONALLY EFFICIENT CHIRAL REDUCING AGENT [J].