Olefination of ketenes for the enantioselective synthesis of allenes via an ylide route

被引：25

作者：

Li, Chuan-Ying ^{[1
]}

Zhu, Ben-Hu

Ye, Long-Wu ^{[1
]}

Jing, Qing ^{[1
]}

Sun, Xiu-Li ^{[1
]}

Tang, Yong ^{[1
]}

Shen, Qi ^{[2
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

[2] Suzhou Univ, Sch Chem & Chem Engn, Suzhou 215123, Peoples R China

来源：

TETRAHEDRON | 2007年 / 63卷 / 33期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/j.tet.2007.05.053

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Pseudo-C-2-symmetric chiral phosphorus ylide is designed and synthesized for the enantioselective preparation of allenic esters, amides, ketone, and nitrile. Up to 92% ee is achieved. (C) 2007 Elsevier Ltd. All rights reserved.

引用

页码：8046 / 8053

页数：8

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