Electrochemical synthesis, voltammetric behavior, and electrocatalytic activity of Pd nanoparticles

被引：146

作者：

Pan, Wei ^{[1
,2
]}

Zhang, Xiaokai ^{[3
,4
]}

Ma, Houyi ^{[1
,2
]}

Zhang, Jintao ^{[2
]}

机构：

[1] Shandong Univ, Key Lab Colloid & Interface Chem, State Educ Min, Jinan 250100, Peoples R China

[2] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China

[3] Shandong Normal Univ, Anal & Testing Ctr, Jinan 250014, Peoples R China

[4] Shandong Normal Univ, Coll Phys & Elect, Jinan 250014, Peoples R China

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2008年 / 112卷 / 07期

关键词：

D O I：

10.1021/jp710092z

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Size-controlled Pd nanoparticles were electrochemically synthesized in large quantities at room temperature through the direct electroreduction of bulk PdCl42- ions in the presence of poly(N-vinylpyrrolidone) (PVP) a water-soluble polymer. The technological key to electrochemical synthesis of Pd particles is that PVP greatly promoted the formation process of Pd particles and inhibited the electrodeposition process of Pd onto the Pt cathode at the same time besides effectively stabilizing the formed Pd nanoparticles. The as-synthesized Pd nanoparticles display the voltammetric behavior significantly different from the bulk Pd and also present a high catalytic activity toward the electrooxidation of methanol.

引用

页码：2456 / 2461

页数：6

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