Revised particle growth model for supported metallocene catalyst co-polymerization

被引：8
作者：
Alexiadis, A. [1 ]
Andes, C. [1 ]
机构：
[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
来源：
APPLIED MATHEMATICAL MODELLING | 2008年 / 32卷 / 01期
关键词：
modelling; metallocene catalyst; co-polymerization;
D O I：
10.1016/j.apm.2006.11.006
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
In this paper, a revised version of the particle growth model (PGM) describing olefin co-polymerization with metallocene catalysts is proposed. The model is used to calculate the reaction rate of hexane-propylene co-polymerization under different operating conditions. Results are compared with experimental data obtained by calorimetric technique in order to validate the model. Good agreement between calculated and experimental results is shown. (C) 2006 Elsevier Inc. All rights reserved.
引用
收藏
页码：99 / 111
页数：13
相关论文
共 18 条
  • [1] Mathematical modeling of homopolymerization on supported metallocene catalysts
    Alexiadis, A
    Andes, C
    Ferrari, D
    Korber, F
    Hauschild, K
    Bochmann, M
    Fink, G
    [J]. MACROMOLECULAR MATERIALS AND ENGINEERING, 2004, 289 (05) : 457 - 466
  • [2] ANDES C, 2003, M EUR RES NETW NEW P
  • [3] PROPYLENE POLYMERIZATION THROUGH SUPPORTED METALLOCENE MAO CATALYSTS - KINETIC-ANALYSIS AND MODELING
    BONINI, F
    FRAAIJE, V
    FINK, G
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1995, 33 (14) : 2393 - 2402
  • [4] Ferrari D, 2006, MACROMOL SYMP, V236, P78, DOI 10.1002/masy.200650410
  • [5] CATALYST FRAGMENTATION DURING PROPYLENE POLYMERIZATION .1. THE EFFECTS OF GRAIN-SIZE AND STRUCTURE
    FERRERO, MA
    CHIOVETTA, MG
    [J]. POLYMER ENGINEERING AND SCIENCE, 1987, 27 (19) : 1436 - 1447
  • [6] POLYMERIZATION OF OLEFINS THROUGH HETEROGENEOUS CATALYSIS .3. POLYMER PARTICLE MODELING WITH AN ANALYSIS OF INTRAPARTICLE HEAT AND MASS-TRANSFER EFFECTS
    FLOYD, S
    CHOI, KY
    TAYLOR, TW
    RAY, WH
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1986, 32 (01) : 2935 - 2960
  • [7] POLYMERIZATION OF OLEFINS THROUGH HETEROGENEOUS CATALYSIS .10. MODELING OF PARTICLE GROWTH AND MORPHOLOGY
    HUTCHINSON, RA
    CHEN, CM
    RAY, WH
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1992, 44 (08) : 1389 - 1414
  • [8] Microkinetic videomicroscopic analysis of olefin polymerization with a supported metallocene catalyst
    Knoke, S
    Ferrari, D
    Tesche, B
    Fink, G
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (41) : 5090 - 5093
  • [9] Early stages of propylene bulk phase polymerization with supported metallocene catalysts
    Knoke, S
    Korber, F
    Fink, G
    Tesche, B
    [J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 2003, 204 (04) : 607 - 617
  • [10] Korber F, 2001, MACROMOL CHEM PHYSIC, V202, P3323, DOI 10.1002/1521-3935(20011101)202:17<3323::AID-MACP3323>3.0.CO
12