Light scattering with swollen hexagonal phases

被引:5
作者
Ramos, L
Fabre, P
Nallet, F
Lu, CYD
机构
[1] Coll France, Lab Phys Fluides Organises, URA 792, CNRS, F-75231 Paris 05, France
[2] CNRS, UMR Elf Atochem, F-92303 Levallois Perret, France
[3] CNRS, Ctr Rech Paul Pascal, F-33600 Pessac, France
[4] Univ Cambridge, Dept Phys, Cambridge CB3 0HE, England
关键词
D O I
10.1007/s101890050030
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We investigate, using quasi-elastic light scattering, some features of the long-wavelength, low-frequency modes of the hexagonal phase often encountered in the study of lyotropic (surfactant-solvent) systems. The hexagonal phase is swollen bg an oil-based ferrofluid, allowing magnetically aligned samples to be prepared. We show experimentally the anisotropy of the two lowest-frequency modes. We develop a model which predicts that these slow modes are associated to particle diffusion and tube motion. With the help of microscopic as well as phenomenological analyses: we suggest that the latter presumably corresponds tu a peristaltic mode. Confinement effects on the one-dimensional, Brownian diffusion of the colloids along the tube axis together with the coupling between the two modes are studied experimentally, varying the tube diameter to particle size ratio.
引用
收藏
页码:285 / 299
页数:15
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