Progress in Transition Metal-Catalyzed Asymmetric Ring-Opening Reactions of Oxa(Aza)bicyclic Alkenes with Carbanion Nucleophiles

被引：8
作者：
Wu, Ruihua [1 ]
Yang, Wen [1 ]
Cheng, Guo [1 ]
Li, Yue [1 ]
Yang, Dingqiao [1 ]
机构：
[1] South China Normal Univ, Key Lab Theoret Chem Environm, Minist Educ, Sch Chem & Environm, Guangzhou 510006, Guangdong, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 36卷 / 10期
基金：
中国国家自然科学基金;
关键词：
transition metal catalyst; oxa(aza)bicyclic alkene; carbanion nucleophile; asymmetric ring-opening; OXABICYCLIC ALKENES; AZABICYCLIC ALKENES; HETEROBICYCLIC ALKENES; BORONIC ACIDS; GRIGNARD; OXABENZONORBORNADIENES; ARYL; REAGENTS; ALKYNES; FUNCTIONALIZATION;
D O I：
10.6023/cjoc201604006
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The recent progress in transition metal-catalyzed asymmetric ring-opening reactions of oxa(aza)bicyclic alkenes with carbanion nucleophiles is reviewed with focus on the influence of the types of transition metal catalysts, carbanion nucleophiles, ligands, the structures of oxa(aza)bicyclic alkenes, solvents and additives on the asymmetric ring-opening reactions. Moreover, the parties of possible mechanisms for the asymmetric ring-opening reactions are also discussed.
引用
收藏
页码：2368 / 2379
页数：12
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