Optimization of Processing Parameters and Macrokinetics for Hydrodenitrogenation of Coal Tar

被引:16
作者
Li, Dong [1 ]
Li, Wenhong [1 ]
Cui, Louwei [1 ]
Yang, Xiaoyan [1 ]
Zhang, Mengxin [1 ]
Yan, Suihong [1 ]
机构
[1] NW Univ Xian, Sch Chem Engn, Xian 710069, Peoples R China
关键词
Coal Tar; Hydrodenitrogenation; Response Surface Methodology; Kinetics Model; GAS OIL; BITUMEN; HYDROTREATMENT; KINETICS;
D O I
10.1166/asl.2011.1460
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Optimization for hydrodenitrogenation (HDN) process conditions of coal tar in a trickle-bed hydrogenation unit were investigated using response surface methodology (RSM). The optimized process conditions were found as: reaction temperature of 704.4 K, hydrogen partial pressure of 13.48 MPa, hydrogen to oil volume ratio of 1600:1 and liquid hourly space velocity (LHSV) of 0.20 h(-1). The kinetics model for HDN of coal tar has been built. Experimental data were fitted by the Levenberg-Marquardt method.
引用
收藏
页码:1514 / 1518
页数:5
相关论文
共 27 条
  • [1] Comparison of hydrodenitrogenation of basic and nonbasic nitrogen compounds present in oil sands derived heavy gas oil
    Bej, SK
    Dalai, AK
    Adjaye, J
    [J]. ENERGY & FUELS, 2001, 15 (02) : 377 - 383
  • [2] HYDROTREATMENT OF ATHABASCA BITUMEN-DERIVED GAS OIL OVER NI-MO, NI-W, AND CO-MO CATALYSTS
    DIAZREAL, RA
    MANN, RS
    SAMBI, IS
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1993, 32 (07) : 1354 - 1358
  • [3] Fang XC., 1996, ACTA PETROLEI SINICA, V12, P19
  • [4] REACTIVITIES, REACTION NETWORKS, AND KINETICS IN HIGH-PRESSURE CATALYTIC HYDROPROCESSING
    GIRGIS, MJ
    GATES, BC
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1991, 30 (09) : 2021 - 2058
  • [5] HYDRODENITROGENATION CATALYSIS
    HO, TC
    [J]. CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1988, 30 (01): : 117 - 160
  • [6] Hu R., 2008, CHINA COAL, V5, P69
  • [7] Katzer J. R., 1979, CATAL REV SCI ENG, V20, P209
  • [8] Catalytic and thermal effects during hydrotreating of bitumen-derived heavy oils
    Kim, JW
    Longstaff, DC
    Hanson, FV
    [J]. FUEL, 1998, 77 (15) : 1815 - 1823
  • [9] HYDROTREATMENT PROCESS KINETICS FOR BITUMEN AND BITUMEN-DERIVED LIQUIDS
    KWAK, S
    LONGSTAFF, DC
    DEO, MD
    HANSON, FV
    [J]. FUEL, 1994, 73 (09) : 1531 - 1536
  • [10] [李冬 Li Dong], 2009, [煤炭转化, Coal Conversion], V32, P81