Enantioselective allylation of ketones catalyzed by chiral In(III)-PYBOX complexes

被引：55

作者：

Lu, J

Hong, ML

Ji, SJ ^{[1
]}

Teo, YC

Loh, TP

机构：

[1] Suzhou Univ, Coll Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215006, Peoples R China

[2] Nanyang Technol Univ, Div Chem & Biol Chem, Singapore 637616, Singapore

[3] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 33期

关键词：

D O I：

10.1039/b507768k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of 20 mol% of chiral catalytic complex prepared from In(OTf)(3) and chiral PYBOX, allyltributylstannane reacted with achiral ketones to afford the corresponding homoallylic alcohols in moderate to high enantioselectivities (54-95 % ee), which constitutes the first example of enantioselective allylation of ketones catalyzed by the chiral In(III)-PYBOX complex.

引用

页码：4217 / 4218

页数：2

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