BINEPINES: chiral binaphthalene-core monophosphepine ligands for multipurpose asymmetric catalysis

被引：61

作者：

Gladiali, Serafino ^{[1
]}

Alberico, Elisabetta ^{[2
]}

Junge, Kathrin ^{[3
]}

Beller, Matthias ^{[3
]}

机构：

[1] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy

[2] CNR, Ist Chim Biomol, I-07040 Maplewood, Italy

[3] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

CHEMICAL SOCIETY REVIEWS | 2011年 / 40卷 / 07期

关键词：

HIGHLY ENANTIOSELECTIVE HYDROGENATION; P-DONOR LIGANDS; PHOSPHORUS LIGANDS; ACID-DERIVATIVES; 3+2 ANNULATIONS; PHOSPHINES; CHEMISTRY; ESTERS; IMINES; CYCLOADDITION;

D O I：

10.1039/c0cs00164c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The atropisomeric structure of 4,5-dihydro-3H-dinaphtho[2,1-c; 1',2'-e] phosphepine is the common axially chiral scaffold of a library of monophosphine ligands nicknamed BINEPINES that have shown a quite remarkable stereoselection efficiency in a broad variety of enantioselective reactions involving the formation of new C-H or C-C or C-X bonds. In this critical review the properties and scope of this type of chiral ligands are illustrated (70 references).

引用

页码：3744 / 3763

页数：20

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